{"id":"W4385268344","doi":"10.1139/cjc-2022-0089","title":"Oxidation of secondary hydroperoxides via αC–H abstraction to form ketones and hydroxyl radicals: fluorene autoxidation as a model system","year":2023,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Regroupement Québécois sur les Matériaux de Pointe; Université du Québec à Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Autoxidation; Chemistry; Radical; Photochemistry; Ketone; Solvent; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002130407,0.0005196205,0.0004724127,0.0001530077,0.0003322838,0.0003348032,0.0004644738,0.0004683129,0.001058875],"category_scores_gemma":[0.0001685738,0.0001633326,0.000422353,0.0001281545,0.0002530015,0.0005767522,0.0002745023,0.0006029684,0.0002133354],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005048992,"about_ca_system_score_gemma":0.0003100241,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001629494,"about_ca_topic_score_gemma":0.001301885,"domain_scores_codex":[0.9999086,0.00001277926,0.000004181781,0.00002945413,0.00002095628,0.0000240566],"domain_scores_gemma":[0.9999214,0.00002433607,0.00001893156,0.000009489929,0.00001352245,0.00001232018],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002334131,0.0003561212,0.001816985,0.000477804,0.00006935091,0.000393865,0.0001314169,0.02399488,0.9584311,0.008363013,0.0005598476,0.005172217],"study_design_scores_gemma":[0.00009652282,0.001169199,0.002059459,0.00001853357,0.00005332682,0.0002226412,0.00008803645,0.1759883,0.8135018,0.00316052,0.003598135,0.00004359164],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9766284,0.001391041,0.01890055,0.0002762131,0.00007426622,0.00009083196,0.0003903999,0.0001107482,0.002137552],"genre_scores_gemma":[0.9926935,0.0008983992,0.004750235,0.0000317642,0.00001228178,0.0000474619,0.0001601398,0.000007557556,0.001398592],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001629494,"threshold_uncertainty_score":0.003663301,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009767540440972819,"score_gpt":0.2187881364445705,"score_spread":0.2090205960035977,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}