{"id":"W4385276377","doi":"10.26434/chemrxiv-2023-ptghf","title":"Polyaromatic phosphetenes: versatile platforms for circularly polarized luminescence generation through chiral perturba-tion","year":2023,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Institute of Circulatory and Respiratory Health; Région Bretagne; Université de Rennes 1; Campus France; Centre National de la Recherche Scientifique; Ministère de l'Enseignement supérieur, de la Recherche et de l'Innovation","keywords":"Stereocenter; Ring (chemistry); Luminescence; HOMO/LUMO; Atomic orbital; Chemistry; Stereochemistry; Crystallography; Materials science; Physics; Molecule; Enantioselective synthesis; Organic chemistry; Optoelectronics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008398499,0.0002237478,0.0001071806,0.0001412562,0.0001063767,0.0002534396,0.000191547,0.0001778536,0.001482395],"category_scores_gemma":[0.00009719721,0.00008070024,0.0001174747,0.0001114404,0.000171685,0.0003170572,0.000225177,0.0003675221,0.0005501356],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001266193,"about_ca_system_score_gemma":0.0001166492,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008697682,"about_ca_topic_score_gemma":0.0001719213,"domain_scores_codex":[0.9999442,0.000008302506,0.000004802043,0.00001614436,0.00001450609,0.00001200861],"domain_scores_gemma":[0.9999433,0.000008738255,0.00001932733,0.00001082362,0.000006740292,0.0000110937],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000067922,0.00002060695,0.0001191014,0.00007155381,0.000004866271,0.0001065217,0.00003083363,0.0003185808,0.992737,0.001127851,0.00007384827,0.005321258],"study_design_scores_gemma":[0.000007280437,0.0001836853,0.0002153993,0.000002170483,0.000003885389,0.0001075188,0.000007925285,0.0003619413,0.9949059,0.0001091379,0.004090857,0.000004346759],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9711736,0.001138138,0.01656579,0.0001153444,0.00004635346,0.00006792593,0.000354445,0.0001956477,0.01034285],"genre_scores_gemma":[0.9863551,0.0005721133,0.009589986,0.00003131975,0.00001276111,0.00004073295,0.0001889694,0.00002901009,0.003179874],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001482395,"threshold_uncertainty_score":0.004959106,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.07510980896506063,"score_gpt":0.2667600350266318,"score_spread":0.1916502260615711,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}