{"id":"W4385332402","doi":"10.1021/jacsau.3c00279","title":"Remarkably Selective Binding, Behavior Modification, and Switchable Release of (Bipyridine)<sub>3</sub>Ru(II) vis-à-vis (Phenanthroline)<sub>3</sub>Ru(II) by Trimeric Cyclophanes in Water","year":2023,"lang":"en","type":"article","venue":"JACS Au","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Department for Employment and Learning, Northern Ireland; Queen's University; Queen's University Belfast; Engineering and Physical Sciences Research Council; China Scholarship Council; Leverhulme Trust; Welch Foundation","keywords":"Bipyridine; Phenanthroline; Chemistry; Luminescence; Cyclophane; Redox; Molecular recognition; Combinatorial chemistry; Molecule; Photochemistry; Stereochemistry; Crystallography; Materials science; Crystal structure; Organic chemistry; Optoelectronics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007011901,0.0002526197,0.0001396454,0.00008139908,0.00007969209,0.0001769652,0.00016611,0.0002106463,0.001578825],"category_scores_gemma":[0.0001292382,0.0001495685,0.0001046041,0.00007515362,0.0001667642,0.0002260079,0.00018377,0.0003035615,0.0003862856],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001252884,"about_ca_system_score_gemma":0.00007821665,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003499743,"about_ca_topic_score_gemma":0.0004630306,"domain_scores_codex":[0.999945,0.000005270884,0.000003098032,0.00001915229,0.00001313217,0.0000142674],"domain_scores_gemma":[0.9999591,0.00001231285,0.00001141701,0.000005477219,0.000004611102,0.00000696267],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002186482,0.000003577396,0.00002973717,0.00001298366,0.000001061014,0.00001745166,0.000009348839,0.00003936534,0.9983354,0.00003364913,0.00006968439,0.001425881],"study_design_scores_gemma":[0.000004846295,0.00006139337,0.0005355647,0.000001498306,0.000002021125,0.00005565212,0.00001160619,0.0007888536,0.9978434,0.00002065753,0.0006717464,0.000002803309],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9874766,0.0006251289,0.007706116,0.0001626585,0.00002355608,0.0000222083,0.0002573988,0.0003865286,0.003339818],"genre_scores_gemma":[0.9862857,0.0006778037,0.007699782,0.00008668518,0.000009908433,0.00005213772,0.0002094071,0.00009350012,0.004884978],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001578825,"threshold_uncertainty_score":0.005281746,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01046775253413128,"score_gpt":0.231706826501352,"score_spread":0.2212390739672208,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}