{"id":"W4385332402","doi":"10.1021/jacsau.3c00279","title":"Remarkably Selective Binding, Behavior Modification, and Switchable Release of (Bipyridine)<sub>3</sub>Ru(II) vis-à-vis (Phenanthroline)<sub>3</sub>Ru(II) by Trimeric Cyclophanes in Water","year":2023,"lang":"en","type":"article","venue":"JACS Au","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Department for Employment and Learning, Northern Ireland; Queen's University; Queen's University Belfast; Engineering and Physical Sciences Research Council; China Scholarship Council; Leverhulme Trust; Welch Foundation","keywords":"Bipyridine; Phenanthroline; Chemistry; Luminescence; Cyclophane; Redox; Molecular recognition; Combinatorial chemistry; Molecule; Photochemistry; Stereochemistry; Crystallography; Materials science; Crystal structure; Organic chemistry; Optoelectronics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0004348715,0.0005145365,0.0006487198,0.0004711009,0.0004970722,0.00005892934,0.000260054,0.000436983,0.00009297844],"category_scores_gemma":[0.0002020318,0.0004717624,0.0001923331,0.001126925,0.000163831,0.0002548955,0.0002149198,0.0004621703,0.00008968101],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002737976,"about_ca_system_score_gemma":0.0001284739,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005273962,"about_ca_topic_score_gemma":0.0001049771,"domain_scores_codex":[0.9966595,0.0001000025,0.0008899487,0.0009725766,0.0005358068,0.0008422273],"domain_scores_gemma":[0.9983912,0.00008165393,0.0003715884,0.0006411434,0.0002627721,0.0002517055],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002247803,0.0003749728,0.001535224,0.0001731737,0.0000647889,0.00004340587,0.000643235,0.0001249383,0.9841147,0.000008146177,0.005520868,0.00717179],"study_design_scores_gemma":[0.001528535,0.0002126921,0.002089916,0.0001084828,0.0001281986,0.00004233404,0.000205046,0.002529212,0.9900363,0.0000591998,0.002497895,0.0005621601],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9979684,0.0002244173,0.00005348301,0.0003078447,0.0002123745,0.00044106,0.00008969234,0.0002261764,0.000476605],"genre_scores_gemma":[0.9971573,0.0009222381,0.00003472066,0.00005097769,0.0001757103,0.0002594994,0.000351429,0.0001258894,0.0009222816],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006609629,"threshold_uncertainty_score":0.9997734,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01046775253413128,"score_gpt":0.231706826501352,"score_spread":0.2212390739672208,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}