{"id":"W4385445729","doi":"10.1107/s2414314623006375","title":"Tetrel bond in the triphenyltin(IV) chloride–cyclohexyldiphenylphosphane oxide (1/1) cocrystal","year":2023,"lang":"en","type":"article","venue":"IUCrData","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Cocrystal; Crystal structure; Chloride; Oxide; Stereochemistry; Crystallography; Hydrogen bond; Medicinal chemistry; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009685987,0.0001981249,0.0004339154,0.0001961869,0.0003231653,0.001231754,0.0006874783,0.0002474925,0.001317909],"category_scores_gemma":[0.0001693219,0.0003212926,0.0001252097,0.0003118205,0.0002734327,0.0002839256,0.0003382158,0.000647951,0.0003935679],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001333679,"about_ca_system_score_gemma":0.000834611,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.01087848,"about_ca_topic_score_gemma":0.01145152,"domain_scores_codex":[0.9998578,0.00000841553,0.000008599716,0.00003926155,0.00005898564,0.0000269316],"domain_scores_gemma":[0.9999521,0.000008136775,0.00001046532,0.000003871381,0.00001171325,0.00001370565],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003712665,0.0001442555,0.001761465,0.0005535523,0.00007026375,0.0009026244,0.0003249519,0.005225197,0.9592183,0.005548038,0.003467448,0.02241267],"study_design_scores_gemma":[0.0003177906,0.0006911727,0.006011297,0.0001143657,0.000146649,0.001249802,0.0004929409,0.02944134,0.920755,0.0006842714,0.04003404,0.00006124122],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9774253,0.002572124,0.002763949,0.0002421585,0.00008923233,0.00003171371,0.0006462637,0.0001889652,0.01604028],"genre_scores_gemma":[0.9877145,0.00164453,0.004939424,0.0001058532,0.00001190899,0.00004152878,0.001284342,0.0000890581,0.004168858],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01087848,"threshold_uncertainty_score":0.02163029,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02000001102686889,"score_gpt":0.2401352978927231,"score_spread":0.2201352868658542,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}