{"id":"W4385515311","doi":"10.1016/j.tetlet.2023.154685","title":"Rhodium-catalyzed ring-opening reactions of heterobicyclic alkenes with heteroarene nucleophiles","year":2023,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Guelph","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Nucleophile; Indole test; Diastereomer; Rhodium; Pyrrole; Catalysis; Ring (chemistry); Coupling reaction; Yield (engineering); Iridium; Medicinal chemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004999871,0.0005521444,0.0002634246,0.00031332,0.0002186105,0.0003143166,0.0007842832,0.0006029155,0.00310119],"category_scores_gemma":[0.0003042897,0.0002188238,0.0003497662,0.0001579183,0.000310929,0.0005764037,0.0005108505,0.0006849128,0.001170764],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003707243,"about_ca_system_score_gemma":0.0002714643,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005792558,"about_ca_topic_score_gemma":0.001502788,"domain_scores_codex":[0.9997031,0.0000440558,0.00001772146,0.00003976786,0.00005077261,0.0001445525],"domain_scores_gemma":[0.9999143,0.00002422958,0.00001617186,0.00001745168,0.000008397998,0.00001946811],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006244555,0.0003043257,0.0003192221,0.000460873,0.00006405997,0.001102963,0.0004583843,0.001279079,0.9631466,0.008964952,0.001545586,0.02172943],"study_design_scores_gemma":[0.0001297465,0.0008687353,0.001514372,0.00003554456,0.0000393391,0.0004905768,0.00006971681,0.002102096,0.9839191,0.0006798708,0.01009979,0.00005126213],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9474751,0.003779095,0.008665005,0.0003784453,0.000227202,0.0001084242,0.0002281937,0.0002228029,0.03891575],"genre_scores_gemma":[0.9935105,0.00120379,0.001370555,0.00005907724,0.00002791612,0.00001683778,0.0001024739,0.00001843616,0.003690385],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00310119,"threshold_uncertainty_score":0.01037455,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02726396551522802,"score_gpt":0.2733676403956325,"score_spread":0.2461036748804045,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}