{"id":"W4385897877","doi":"10.1021/acs.jpclett.3c01694","title":"Higher-Order Multidimensional and Pump–Probe Spectroscopies","year":2023,"lang":"en","type":"review","venue":"The Journal of Physical Chemistry Letters","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Stiftung Begabtenförderung Cusanuswerk; Deutsche Forschungsgemeinschaft; Alexander von Humboldt-Stiftung","keywords":"Spectroscopy; Excited state; Excitation; Coherent spectroscopy; Absorption spectroscopy; Ultrafast laser spectroscopy; Physics; Atomic physics; Chemistry; Optics; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007055767,0.0007962396,0.0009685419,0.002616083,0.0003133248,0.001002783,0.0008214149,0.0009100349,0.002717378],"category_scores_gemma":[0.0005479541,0.0004350618,0.0004229393,0.001701446,0.0005303189,0.001452451,0.0006648521,0.001473899,0.002329851],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007117179,"about_ca_system_score_gemma":0.0006726249,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000765584,"about_ca_topic_score_gemma":0.0009196247,"domain_scores_codex":[0.9997792,0.00002846855,0.00001470136,0.00004572958,0.000100697,0.00003128457],"domain_scores_gemma":[0.9998067,0.0000700088,0.00002353423,0.00001495357,0.00006308089,0.000021771],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00006625324,0.0001792391,0.0002439091,0.01715514,0.00009954748,0.0003396923,0.0001376294,0.001260704,0.01773836,0.05588442,0.02266751,0.8842276],"study_design_scores_gemma":[0.000009264813,0.00007966447,0.0005964442,0.00075675,0.00002709817,0.0008275997,0.00003127224,0.0002933062,0.005229855,0.005701864,0.9864175,0.00002932252],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.0005987052,0.9927313,0.001150771,0.0002832079,0.0002578957,0.00001706733,0.00003569257,0.00001962469,0.004905811],"genre_scores_gemma":[0.00517028,0.9891991,0.001944125,0.0002561696,0.000291436,0.0000492764,0.00006920905,0.000006675014,0.003013716],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.002717378,"threshold_uncertainty_score":0.009090543,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02540932131177884,"score_gpt":0.309631231783659,"score_spread":0.2842219104718802,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}