{"id":"W4385986198","doi":"10.26434/chemrxiv-2023-3h56n","title":"Stereospecific single step cyclization to give belt-functionalized pillar[6]arenes","year":2023,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"Australian Research Council; National Cancer Institute; Australian Government; Australian Synchrotron; National Computational Infrastructure","keywords":"Pillar; Substituent; Stereospecificity; Chemistry; Single crystal; Crystallography; Stereochemistry; Polymer chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007399279,0.0003937777,0.000245049,0.000253582,0.000135026,0.0002141426,0.0002258964,0.0001744928,0.004442418],"category_scores_gemma":[0.0001301436,0.0001531636,0.0002154217,0.0001411569,0.0001191001,0.0002820222,0.0002532662,0.0004297807,0.001371753],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000141453,"about_ca_system_score_gemma":0.0001615671,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001999113,"about_ca_topic_score_gemma":0.0005494109,"domain_scores_codex":[0.999918,0.000005488989,0.000007481767,0.0000250671,0.0000174626,0.00002651935],"domain_scores_gemma":[0.9999462,0.000005276594,0.00001285742,0.0000104006,0.000009632115,0.00001560935],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007645776,0.00004590369,0.0001278288,0.00009680673,0.00001340079,0.0001892669,0.00004795156,0.0004749979,0.9871242,0.001558972,0.000222065,0.01002214],"study_design_scores_gemma":[0.00002699387,0.0005405564,0.001333427,0.000008816168,0.00001522002,0.0003258708,0.0000184032,0.0008732715,0.9815158,0.0003059105,0.0150172,0.00001860314],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9536375,0.002066594,0.02202485,0.0002125963,0.0001978843,0.000315233,0.001065278,0.0006374153,0.01984247],"genre_scores_gemma":[0.9775999,0.001422985,0.01311743,0.00009058287,0.00002807486,0.0001245943,0.0006814048,0.0000887917,0.006846196],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004442418,"threshold_uncertainty_score":0.0148614,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05956339581789725,"score_gpt":0.2680803570254368,"score_spread":0.2085169612075396,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}