{"id":"W4386019710","doi":"10.1002/chem.202301915","title":"Hydrogenation of CO<sub>2</sub> by a Bifunctional PC(<i>sp</i><sup><i>3</i></sup>)P Iridium(III) Pincer Complex Equipped with Tertiary Amine as a Functional Group","year":2023,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Institute of Circulatory and Respiratory Health; Universität Leipzig; Israel Science Foundation; German-Israeli Foundation for Scientific Research and Development","keywords":"Formic acid; Bifunctional; Iridium; Catalysis; Pincer movement; Amine gas treating; Chemistry; Ton; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008984111,0.0003395255,0.0001943141,0.000128678,0.0001270252,0.0003207695,0.0003773749,0.00029775,0.001243376],"category_scores_gemma":[0.0001958748,0.0001247506,0.0001214757,0.0001317629,0.0002614873,0.0002526153,0.0002631001,0.0002695377,0.0002669277],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002708123,"about_ca_system_score_gemma":0.0001643305,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009356741,"about_ca_topic_score_gemma":0.001019163,"domain_scores_codex":[0.999907,0.00000915199,0.000004652879,0.0000229441,0.00002452051,0.00003166959],"domain_scores_gemma":[0.9999598,0.000006389432,0.00001085574,0.000004616342,0.000006693801,0.00001163776],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002173203,0.00002498517,0.0001635345,0.0001083811,0.00001364652,0.0001199182,0.00002736352,0.0004315239,0.9949223,0.0004508976,0.0002024756,0.00331765],"study_design_scores_gemma":[0.000005550485,0.00007229279,0.0002033266,0.000001328022,0.000005379971,0.00006073972,0.00000617357,0.0009405708,0.9978758,0.00001361254,0.0008118039,0.000003410494],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9912758,0.0004690484,0.003797854,0.00007542111,0.00004273845,0.00002541704,0.00009720488,0.0001356415,0.004080874],"genre_scores_gemma":[0.9974017,0.0001073433,0.001374607,0.00001604581,0.000003066823,0.000005733057,0.00006018702,0.000015737,0.001015689],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001243376,"threshold_uncertainty_score":0.00415951,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01443524040221059,"score_gpt":0.2134072629851374,"score_spread":0.1989720225829268,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}