{"id":"W4386022563","doi":"10.1021/acs.jpclett.3c01675","title":"Coupling of N<sub>2</sub> and O<sub>2</sub> in the Gas Phase to Synthesize Nitric Oxide at Room Temperature: A Zeldovich-Like Strategy","year":2023,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry Letters","topic":"Ammonia Synthesis and Nitrogen Reduction","field":"Chemical Engineering","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ministry of Education and Child Care","funders":"Beijing Municipal Natural Science Foundation; National Natural Science Foundation of China","keywords":"Coupling (piping); Nitric oxide; Nitric acid; Phase (matter); Gas phase; Oxide; Materials science; Analytical Chemistry (journal); Thermodynamics; Chemistry; Physics; Inorganic chemistry; Metallurgy; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001051524,0.0002908327,0.0001780763,0.00006252676,0.00009154357,0.0001165155,0.0002636859,0.0002592017,0.0008236439],"category_scores_gemma":[0.0001191766,0.0001129757,0.0001195189,0.00004431761,0.0001621619,0.0002278121,0.0001977621,0.0002432683,0.0003604242],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002138939,"about_ca_system_score_gemma":0.0001581142,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003840733,"about_ca_topic_score_gemma":0.001369737,"domain_scores_codex":[0.999925,0.00001054258,0.00000355876,0.00002164284,0.00002201534,0.0000171952],"domain_scores_gemma":[0.9999689,0.000007774603,0.000009051759,0.000004801122,0.000004915315,0.000004589396],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004972161,0.00001585919,0.00008256891,0.0001155104,0.000008376379,0.00006560255,0.00002613105,0.0003003024,0.9953617,0.0009640822,0.0001318885,0.002878117],"study_design_scores_gemma":[0.00000925094,0.0001207846,0.0003305543,0.000003602987,0.000006301906,0.0001024457,0.00001827078,0.000984808,0.9926368,0.0002408038,0.005540098,0.000006330034],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9186293,0.003755997,0.05950864,0.0003293482,0.0003038276,0.0002178687,0.0001849802,0.0002835036,0.01678651],"genre_scores_gemma":[0.9676086,0.00130118,0.023045,0.0001820703,0.00002052803,0.00009185855,0.00009570563,0.000041402,0.007613697],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008236439,"threshold_uncertainty_score":0.002755344,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009684115248146974,"score_gpt":0.2276618968488969,"score_spread":0.2179777816007499,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}