{"id":"W4386022563","doi":"10.1021/acs.jpclett.3c01675","title":"Coupling of N<sub>2</sub> and O<sub>2</sub> in the Gas Phase to Synthesize Nitric Oxide at Room Temperature: A Zeldovich-Like Strategy","year":2023,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry Letters","topic":"Ammonia Synthesis and Nitrogen Reduction","field":"Chemical Engineering","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ministry of Education and Child Care","funders":"Beijing Municipal Natural Science Foundation; National Natural Science Foundation of China","keywords":"Coupling (piping); Nitric oxide; Nitric acid; Phase (matter); Gas phase; Oxide; Materials science; Analytical Chemistry (journal); Thermodynamics; Chemistry; Physics; Inorganic chemistry; Metallurgy; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006035584,0.0002758391,0.0004471156,0.00007479935,0.0001031777,0.00003653732,0.000411161,0.00008489909,0.000003933144],"category_scores_gemma":[0.0001755546,0.0001795687,0.0002162124,0.0006117165,0.0001007551,0.0001117993,0.00008637734,0.0006693095,0.000009932986],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001120292,"about_ca_system_score_gemma":0.00003181931,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005632884,"about_ca_topic_score_gemma":7.886125e-7,"domain_scores_codex":[0.9983463,0.00005010237,0.0005056222,0.0002046067,0.0005107185,0.0003826863],"domain_scores_gemma":[0.9984375,0.0007865578,0.0002802083,0.0002915821,0.00006070485,0.0001434184],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002702639,0.0001324497,0.00001711249,0.0001017036,0.00008583688,0.00004637628,0.000288669,0.01740114,0.9805213,0.000004959559,0.0005358033,0.000594345],"study_design_scores_gemma":[0.0005450891,0.00003548761,0.0001860896,0.0001590151,0.0001319403,0.0001384037,0.0004476598,0.005941586,0.9921783,0.00003031079,0.00001606116,0.0001900247],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.998165,0.0001502315,0.00004671362,0.001440681,0.00002660261,0.0001229226,0.00001088076,0.00002608363,0.00001094762],"genre_scores_gemma":[0.9992481,0.00007498536,0.00001344322,0.0001452886,0.0004626353,0.000009795286,0.000003582433,0.00003923133,0.000002943733],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01165699,"threshold_uncertainty_score":0.7322599,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009684115248146974,"score_gpt":0.2276618968488969,"score_spread":0.2179777816007499,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}