{"id":"W4386046201","doi":"10.1021/acs.biomac.3c00513","title":"Effect of Surface Functionality on the Rheological and Self-Assembly Properties of Chitin and Chitosan Nanocrystals and Use in Biopolymer Films","year":2023,"lang":"en","type":"article","venue":"Biomacromolecules","topic":"Advanced Cellulose Research Studies","field":"Materials Science","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada; McGill University","funders":"National Research Council Canada; Canada Foundation for Innovation; Natural Sciences and Engineering Research Council of Canada; McGill University","keywords":"Nanocrystal; Biopolymer; Chemical engineering; Materials science; Chitosan; Carboxylation; Chitin; Chemistry; Polymer chemistry; Nanotechnology; Organic chemistry; Composite material; Polymer; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001464712,0.0003177013,0.0001221383,0.0001091807,0.00007534974,0.0001829173,0.000138152,0.0002175809,0.0007481866],"category_scores_gemma":[0.0002972752,0.000130301,0.0001451179,0.0001230184,0.0001432897,0.0001629435,0.00009598912,0.0002945168,0.0001174219],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001841733,"about_ca_system_score_gemma":0.0001402331,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001083888,"about_ca_topic_score_gemma":0.002430568,"domain_scores_codex":[0.999867,0.00001919169,0.00001856622,0.00002720514,0.00004247331,0.00002560935],"domain_scores_gemma":[0.9997794,0.00007975626,0.0000522615,0.00001880164,0.00003399793,0.00003589203],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003153798,0.000009859229,0.0000728784,0.00002096459,0.000002100403,0.00001755251,0.000007660199,0.00002730377,0.9994031,0.000009998485,0.000004550467,0.0003923737],"study_design_scores_gemma":[0.00000270089,0.0001098557,0.001439304,0.000001600128,0.000005037153,0.00002421632,0.000006651414,0.0002184423,0.9980145,0.000002738976,0.0001726794,0.000002369546],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9980929,0.0003185474,0.0006390188,0.00002015227,0.000007833816,0.00001667344,0.00008355043,0.00001667376,0.000804528],"genre_scores_gemma":[0.9973705,0.0002768273,0.001401087,0.00001777431,0.000002535912,0.00001837469,0.00009947257,0.000009843916,0.0008036168],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001083888,"threshold_uncertainty_score":0.002502918,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02567422102481943,"score_gpt":0.2729552866277091,"score_spread":0.2472810656028896,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}