{"id":"W4386169123","doi":"10.1021/acs.organomet.3c00204","title":"Alkali Metal Amide Salts of a Bulky Nitrogen Tethered Phosphonium Fluorenide Ligand","year":2023,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saint Mary's University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Enamine; Deprotonation; Phosphonium; Ligand (biochemistry); Medicinal chemistry; Molecule; Stereochemistry; Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006074367,0.0001891858,0.0001498703,0.0000827593,0.00008462039,0.0001547287,0.0003037708,0.0001996086,0.001342568],"category_scores_gemma":[0.0000886983,0.00009041419,0.00007264303,0.0001033657,0.0001110517,0.0001769785,0.0001866353,0.0002449319,0.0003804586],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002937011,"about_ca_system_score_gemma":0.0001797068,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009872476,"about_ca_topic_score_gemma":0.001718324,"domain_scores_codex":[0.9999471,0.000006354749,0.000004141104,0.00001078111,0.00001523803,0.00001637651],"domain_scores_gemma":[0.9999697,0.000004789318,0.000008388554,0.000003303862,0.000004517955,0.000009343287],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001099477,0.00001138469,0.00008560214,0.00008586526,0.000004288851,0.00006204462,0.00002418928,0.0002455153,0.9974054,0.0002277197,0.00009514394,0.001642864],"study_design_scores_gemma":[0.00003021601,0.000261842,0.000607105,0.000008983553,0.000007613721,0.0001017159,0.00001539602,0.000934282,0.9936954,0.0000430613,0.004287506,0.000006988542],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"methods","genre_scores_codex":[0.9927267,0.0005798795,0.001409836,0.00005006741,0.00002072083,0.00001586759,0.000148878,0.000107929,0.00494023],"genre_scores_gemma":[0.9927644,0.0003979162,0.002090953,0.00002495451,0.000006913906,0.00001229574,0.0001975084,0.00001623186,0.004488887],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.001342568,"threshold_uncertainty_score":0.004491329,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01957058458669279,"score_gpt":0.2606723225370393,"score_spread":0.2411017379503465,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}