{"id":"W4386316698","doi":"10.1002/chem.202302810","title":"Cover Feature: Base‐Stabilized Phosphinidene Oxide, Imide and Sulfide (Chem. Eur. J. 59/2023)","year":2023,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"","keywords":"Phosphinidene; Chemistry; Medicinal chemistry; Sulfide; Isocyanate; Base (topology); Sulfur; Polymer chemistry; Oxide; Imide; Stereochemistry; Organic chemistry; Mathematics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.001353536,0.0006814125,0.0006315657,0.00008219641,0.0005469085,0.0005738839,0.0009903554,0.0001832972,0.00739904],"category_scores_gemma":[0.001378425,0.0006798299,0.000348152,0.000586934,0.0002891122,0.0002818281,0.0006116249,0.001504331,0.001381088],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002514933,"about_ca_system_score_gemma":0.0001965506,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006083381,"about_ca_topic_score_gemma":6.172757e-7,"domain_scores_codex":[0.9963648,0.00014121,0.0008359394,0.0008876739,0.0007556149,0.001014749],"domain_scores_gemma":[0.9969954,0.0004503917,0.0005052455,0.001010533,0.0002035517,0.0008348948],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001622874,0.00007198931,0.001973667,0.0002325349,0.0001549873,0.002156055,0.000135661,0.00002006597,0.901216,0.00000167533,0.0921456,0.001729421],"study_design_scores_gemma":[0.002402535,0.00001822018,0.003150853,0.0003329709,0.0001460179,0.002331309,0.0004410588,0.0005668039,0.8531561,0.00008760262,0.1364678,0.0008986628],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9511096,0.001868639,0.00002168566,0.001304381,0.0002103856,0.00006632385,0.00008805101,0.0004871718,0.04484373],"genre_scores_gemma":[0.9475236,0.001758774,0.001231228,0.0002650408,0.001097824,0.000008525407,0.0000798346,0.0003459471,0.04768922],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04805993,"threshold_uncertainty_score":0.9995653,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01280364777773666,"score_gpt":0.2082916939021788,"score_spread":0.1954880461244421,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}