{"id":"W4386376467","doi":"10.1002/adsc.202300801","title":"Synthetic Study on the Lycoricidine Alkaloids","year":2023,"lang":"en","type":"article","venue":"Advanced Synthesis & Catalysis","topic":"Chemical synthesis and alkaloids","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal","funders":"","keywords":"Chemistry; Stereoselectivity; Dihydroxylation; Hypervalent molecule; Total synthesis; Natural product; Diastereomer; Stereochemistry; Combinatorial chemistry; Organic chemistry; Enantioselective synthesis; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002177767,0.0004172388,0.0003438916,0.0002800729,0.0002581164,0.0002085162,0.0003201432,0.0002908519,0.00191239],"category_scores_gemma":[0.0002385028,0.0001165825,0.0002526235,0.0002855427,0.0001919109,0.0002856337,0.0002996643,0.0005385798,0.001009887],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002484337,"about_ca_system_score_gemma":0.0004612555,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005074987,"about_ca_topic_score_gemma":0.001025783,"domain_scores_codex":[0.9998492,0.00002859882,0.00001625857,0.00003585899,0.00003928121,0.00003078229],"domain_scores_gemma":[0.9998678,0.00001527906,0.00002064042,0.00002618709,0.00003729717,0.0000328134],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001029788,0.00007934726,0.0001933821,0.0003180875,0.00001437659,0.0005906688,0.00009210169,0.0003796495,0.9881297,0.0008161513,0.0001598266,0.00912374],"study_design_scores_gemma":[0.00006557063,0.001538189,0.001105214,0.00003593495,0.00004134115,0.0008793683,0.00005479812,0.000481566,0.9730961,0.0002464471,0.02243545,0.00001998161],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9062487,0.01073506,0.03017566,0.0004366402,0.000303921,0.00105072,0.002096155,0.0002226251,0.04873052],"genre_scores_gemma":[0.9692777,0.005295301,0.0180074,0.0001769516,0.00007024735,0.0001093947,0.001026295,0.00004673805,0.005989977],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00191239,"threshold_uncertainty_score":0.006397545,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02124521546607403,"score_gpt":0.2549128255593791,"score_spread":0.233667610093305,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}