{"id":"W4386478117","doi":"10.1002/smll.202370284","title":"The Effect of Linker‐to‐Metal Energy Transfer on the Photooxidation Performance of an Isostructural Series of Pyrene‐Based Rare‐Earth Metal–Organic Frameworks (Small 36/2023)","year":2023,"lang":"en","type":"article","venue":"Small","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; McGill University; Concordia University","funders":"","keywords":"Isostructural; Singlet oxygen; Pyrene; Photochemistry; Chemistry; Metal; Metal-organic framework; Sulfide; Excited state; Metal ions in aqueous solution; Linker; Bimetallic strip; Inorganic chemistry; Oxygen; Organic chemistry; Adsorption","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005849309,0.0002851511,0.0004579876,0.00008321588,0.0001986631,0.0000330431,0.0006815281,0.0003407602,0.0007280508],"category_scores_gemma":[0.0003074328,0.0001705539,0.0002458586,0.0007212086,0.0002117276,0.00007173901,0.00006200477,0.0004569502,0.00001695896],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001585112,"about_ca_system_score_gemma":0.00006263191,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003997106,"about_ca_topic_score_gemma":0.0001184714,"domain_scores_codex":[0.9982616,0.0001513384,0.0005942694,0.0003395639,0.0003420086,0.0003112498],"domain_scores_gemma":[0.9974859,0.001091846,0.0002132649,0.001026114,0.0001094521,0.00007335733],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00043306,0.00004958785,0.0001852037,0.0001925635,0.0001461336,5.884733e-7,0.0001913023,0.0005403782,0.9852189,0.002044203,0.0000277672,0.01097029],"study_design_scores_gemma":[0.0002604191,0.0004088327,0.001231731,0.0001533105,0.0001227714,0.000001915691,0.000132985,0.00355522,0.9928149,0.0001485158,0.0009974281,0.0001719615],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9981495,0.00009868199,0.0004005043,0.0004333002,0.0001043641,0.0002464569,0.00008354335,0.00006308538,0.0004205599],"genre_scores_gemma":[0.9985052,0.0000867316,0.0003113851,0.00007535661,0.00009447193,0.0001209565,0.00006699797,0.00005065712,0.0006882704],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01079832,"threshold_uncertainty_score":0.7971645,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0125699772607718,"score_gpt":0.2164011394146271,"score_spread":0.2038311621538553,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}