{"id":"W4386507881","doi":"10.1021/acs.inorgchem.3c02039","title":"Multicomponent Synthesis of Poly(α-aminophosphine chalcogenide)s and Subsequent Depolymerization","year":2023,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada; Western University; Canada Foundation for Innovation; Solvay; Nuclear Waste Management Organization","keywords":"Chemistry; Depolymerization; Chalcogenide; Polymer science; Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00005325409,0.0001966996,0.0002769259,0.00002703904,0.00008055857,0.00001676217,0.0001690968,0.0001933224,0.001137754],"category_scores_gemma":[0.0002603904,0.0001884843,0.00009720843,0.0002522003,0.0001215153,0.00004207079,0.0001305095,0.0001415416,0.00002115125],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005022715,"about_ca_system_score_gemma":0.00003576367,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009290595,"about_ca_topic_score_gemma":0.000001492047,"domain_scores_codex":[0.9987953,0.000004946111,0.0003725979,0.0003347777,0.000228886,0.0002634751],"domain_scores_gemma":[0.999079,0.0002387586,0.0001613192,0.000350303,0.00002746222,0.0001431872],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001320529,0.00008716463,0.002769234,0.0004056649,0.00005987426,0.000007968192,0.00005673712,0.000001083609,0.9892282,0.00000915353,0.0000232082,0.00733848],"study_design_scores_gemma":[0.0002044806,0.000001831576,0.001386194,0.00008637088,0.00005479185,0.0000350281,0.0001695133,0.0002776918,0.9971043,0.00002579124,0.0004550728,0.0001988981],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9955196,0.000702375,0.00000845345,0.0002786331,0.00003932861,0.00003348004,0.00007495918,0.0001888015,0.003154363],"genre_scores_gemma":[0.9986264,0.0005019026,0.00005282629,0.000009131774,0.0001247182,0.00002433251,0.00006094883,0.00003868229,0.0005610666],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00787611,"threshold_uncertainty_score":0.9997754,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01086262510231233,"score_gpt":0.2165069885632408,"score_spread":0.2056443634609285,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}