{"id":"W4386600577","doi":"10.1002/ejoc.202300731","title":"Metal‐Free Defluoroborylation of 3,3‐Difluoropropenes","year":2023,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval; PROTEO","funders":"Natural Sciences and Engineering Research Council of Canada; Université de Bordeaux; Agence Nationale de la Recherche; Centre National de la Recherche Scientifique; Université Laval","keywords":"Chemistry; Diborane; Nucleophile; Allylic rearrangement; Surface modification; Combinatorial chemistry; Transition metal; Fluoride; Molecule; Nucleophilic substitution; Reactivity (psychology); Organic chemistry; Catalysis; Inorganic chemistry; Boron","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001509905,0.0004185502,0.0001513331,0.0001973101,0.000159124,0.0001336628,0.0001930393,0.0002365268,0.002471707],"category_scores_gemma":[0.0001232566,0.0001105821,0.0001659693,0.0001278917,0.0001382864,0.000247807,0.0002304995,0.0003267497,0.0005787301],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001904389,"about_ca_system_score_gemma":0.0002360323,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006225173,"about_ca_topic_score_gemma":0.001111241,"domain_scores_codex":[0.9999191,0.00001217996,0.000004379682,0.00001432486,0.00001420298,0.00003587213],"domain_scores_gemma":[0.9999589,0.000007056738,0.00001082568,0.000005780948,0.000007304096,0.00001019912],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001681614,0.00002552064,0.00009947265,0.0002005199,0.00001226273,0.0001689691,0.00005962036,0.0002338088,0.9912135,0.0009034137,0.0001771581,0.006737513],"study_design_scores_gemma":[0.0000130438,0.0001707774,0.0004871065,0.00001084864,0.000007590103,0.0001787049,0.00001484968,0.0001793586,0.9923962,0.0000959644,0.006437095,0.000008530795],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9646581,0.005007867,0.01592529,0.0002551346,0.0001291028,0.00008933564,0.0006910698,0.0002333895,0.0130107],"genre_scores_gemma":[0.9907367,0.001668454,0.003650879,0.00005730898,0.00001068209,0.00002145927,0.0002765561,0.00002648855,0.003551574],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002471707,"threshold_uncertainty_score":0.008268714,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.08201648858948044,"score_gpt":0.3656322112017795,"score_spread":0.2836157226122991,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}