{"id":"W4386623646","doi":"10.1002/chem.202302914","title":"Tracking SF<sub>5</sub>I in the Iodopentafluorosulfanylation of Alkynes","year":2023,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"Centre in Green Chemistry and Catalysis; Université de Sherbrooke","funders":"European Regional Development Fund; Alliance de recherche numérique du Canada; Institut Carnot Santé Animale; Université de Rouen; Centre National de la Recherche Scientifique; Université de Strasbourg; Agence Nationale de la Recherche; Indian National Science Academy","keywords":"Chemistry; Reagent; Stereoselectivity; Radical; Sulfanyl; Iodine; Halogenation; Medicinal chemistry; Combinatorial chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001336246,0.0001768175,0.0001100504,0.00005618213,0.00008212198,0.0002239534,0.0002126287,0.0001908952,0.001082011],"category_scores_gemma":[0.0001231758,0.00005624742,0.0001253188,0.00007293566,0.0001482348,0.0002272283,0.0001768913,0.0002069374,0.0002725405],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001909053,"about_ca_system_score_gemma":0.0001532415,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005285771,"about_ca_topic_score_gemma":0.0005696298,"domain_scores_codex":[0.9999504,0.000007204964,0.000002460411,0.00001076941,0.00001091608,0.00001814014],"domain_scores_gemma":[0.9999641,0.000009158241,0.00001460914,0.000004213809,0.000004175395,0.000003705603],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003382687,0.00004141992,0.0006018428,0.0002347691,0.0000159733,0.0002236634,0.0001667218,0.003155511,0.9797503,0.003361182,0.0002081935,0.01190221],"study_design_scores_gemma":[0.00002881079,0.0005107324,0.0005436171,0.0000109795,0.00001212745,0.0001040929,0.00004950594,0.003505641,0.9900542,0.0003076235,0.004861302,0.00001130728],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9876614,0.0005575884,0.007501183,0.00006155544,0.00001490534,0.00002645846,0.00009280165,0.00007123945,0.004012902],"genre_scores_gemma":[0.9967548,0.0003684258,0.001970561,0.00001472384,0.000001826379,0.000007968353,0.00003656289,0.000009825707,0.0008352962],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001082011,"threshold_uncertainty_score":0.003619671,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1168460681554289,"score_gpt":0.3803204492689943,"score_spread":0.2634743811135654,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}