{"id":"W4386634374","doi":"10.1002/kin.21691","title":"Measurement and modeling of peroxides half‐life: A thermo‐kinetic approach","year":2023,"lang":"en","type":"article","venue":"International Journal of Chemical Kinetics","topic":"Thermal and Kinetic Analysis","field":"Materials Science","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dow Chemical (Canada)","funders":"","keywords":"Kinetic energy; Isothermal process; Chemistry; Thermodynamics; Reactivity (psychology); Kinetics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001502404,0.001036745,0.0006402071,0.001182957,0.0002225101,0.0007271231,0.001076329,0.0008915871,0.001273271],"category_scores_gemma":[0.002023136,0.0005505169,0.001198903,0.000837135,0.0003373168,0.001336204,0.000376922,0.001275823,0.0009781193],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0009192282,"about_ca_system_score_gemma":0.0006906445,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001505582,"about_ca_topic_score_gemma":0.00126777,"domain_scores_codex":[0.9994104,0.00007003553,0.00004068962,0.0001615863,0.000270815,0.00004641589],"domain_scores_gemma":[0.999266,0.0002877209,0.0001085392,0.00009764306,0.0002268456,0.00001329662],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"simulation_or_modeling","study_design_scores_codex":[0.0004538439,0.0003189748,0.007931303,0.002154016,0.0001622468,0.0001943349,0.0003792901,0.1156515,0.7786965,0.006316669,0.001522239,0.08621899],"study_design_scores_gemma":[0.00001493713,0.0004211736,0.004996232,0.00007780009,0.0001146998,0.0002317794,0.00009364733,0.3947602,0.5870264,0.002641588,0.009543832,0.00007781374],"study_design_candidate":"simulation_or_modeling","study_design_consensus":null,"genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.2559055,0.007710695,0.7274016,0.0002547631,0.0001797363,0.0003987568,0.001891839,0.001414431,0.004842739],"genre_scores_gemma":[0.8815,0.007400676,0.101195,0.0001022435,0.00003049443,0.0008746461,0.001948454,0.0002330717,0.006715431],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.001505582,"threshold_uncertainty_score":0.007945597,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04562178520750329,"score_gpt":0.2657440474050889,"score_spread":0.2201222621975856,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}