{"id":"W4386693628","doi":"10.1039/d3dt02304d","title":"A novel access to phosphanylidene–phosphorane complexes<i>via</i>P-donor substitution and a detailed bonding analysis","year":2023,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"Universidad de Murcia; Deutsche Forschungsgemeinschaft","keywords":"Phosphorane; Substitution (logic); Chemistry; Crystallography; Stereochemistry; Computer science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002443766,0.0003823073,0.0005821578,0.000679397,0.0006690083,0.000344401,0.0004768595,0.0001789825,0.002229955],"category_scores_gemma":[0.00004932952,0.0004298967,0.0003037441,0.004125419,0.0001117059,0.0004637071,0.00005191495,0.0002847392,0.0002327088],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002273419,"about_ca_system_score_gemma":0.00007374785,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001133489,"about_ca_topic_score_gemma":0.001678163,"domain_scores_codex":[0.997562,0.00002126828,0.0005474968,0.0007991547,0.0004279031,0.0006422154],"domain_scores_gemma":[0.9984237,0.0002963188,0.0001261798,0.0006542561,0.0001061147,0.00039344],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000205221,0.0003183887,0.01228953,0.0001966263,0.001525234,0.00003471468,0.000833268,0.004497683,0.9716615,0.0002260364,0.0003366756,0.007875092],"study_design_scores_gemma":[0.001176049,0.00003248981,0.02525563,0.00008790389,0.002229954,0.00004444177,0.0003373536,0.01230421,0.9420624,0.0001411169,0.01538817,0.0009402264],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8100201,0.0001869232,0.185993,0.001218916,0.0002265071,0.0002704202,0.0004546657,0.0008690903,0.0007602875],"genre_scores_gemma":[0.9956064,0.0001158916,0.001777211,0.0001473403,0.00006000022,0.0002024029,0.0001379449,0.00006787623,0.001884944],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1855862,"threshold_uncertainty_score":0.9998153,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.027479780949016,"score_gpt":0.2705147174620791,"score_spread":0.2430349365130631,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}