{"id":"W4386693628","doi":"10.1039/d3dt02304d","title":"A novel access to phosphanylidene–phosphorane complexes<i>via</i>P-donor substitution and a detailed bonding analysis","year":2023,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"Universidad de Murcia; Deutsche Forschungsgemeinschaft","keywords":"Phosphorane; Substitution (logic); Chemistry; Crystallography; Stereochemistry; Computer science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008730796,0.000342001,0.0002769352,0.0001086217,0.0003025938,0.0003829492,0.0007010825,0.0002767821,0.003093685],"category_scores_gemma":[0.0001432869,0.0002201191,0.0001659934,0.0001476308,0.0002010241,0.0004263361,0.0005120694,0.0005680778,0.0006291539],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002944441,"about_ca_system_score_gemma":0.0002332419,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003933447,"about_ca_topic_score_gemma":0.0005290192,"domain_scores_codex":[0.9999299,0.000007731896,0.000005307425,0.0000204789,0.00001854764,0.00001787074],"domain_scores_gemma":[0.9999626,0.000005960735,0.00001101657,0.000009329225,0.000004841636,0.000006267719],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001999634,0.0001271107,0.0002385698,0.0005899888,0.00003351659,0.0006642101,0.0002610116,0.0009877918,0.9621601,0.01169517,0.001509562,0.02153312],"study_design_scores_gemma":[0.00004709042,0.000583566,0.0005484885,0.00001426297,0.00002162418,0.001181468,0.00004754093,0.002133712,0.9716812,0.0008957962,0.0228169,0.00002829053],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9066351,0.002011647,0.04241329,0.0004183824,0.0001273568,0.0002196888,0.0006394981,0.0006785084,0.04685665],"genre_scores_gemma":[0.9799498,0.001274932,0.01226289,0.0000826016,0.00001914023,0.00009337947,0.0003243051,0.000105816,0.005887233],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003093685,"threshold_uncertainty_score":0.01034945,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.027479780949016,"score_gpt":0.2705147174620791,"score_spread":0.2430349365130631,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}