{"id":"W4386981059","doi":"10.1007/s43630-023-00473-7","title":"A laser flash photolysis study of the free radical chemistry of lipoic acid and dihydrolipoic acid","year":2023,"lang":"en","type":"article","venue":"Photochemical & Photobiological Sciences","topic":"Biochemical Acid Research Studies","field":"Biochemistry, Genetics and Molecular Biology","cited_by":1,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Canada Foundation for Innovation","keywords":"Chemistry; Radical; Flash photolysis; Photochemistry; Hydrogen atom; Chromophore; Photodissociation; Lipoic acid; Hydrogen; Ketyl; Organic chemistry; Antioxidant; Kinetics; Reaction rate constant","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000138047,0.0001897306,0.0001893486,0.0002172439,0.0003095885,0.0001907381,0.0002643744,0.0003652491,0.003613856],"category_scores_gemma":[0.0001495042,0.0001212635,0.0002255677,0.0001876365,0.0003280647,0.0003864108,0.0001339716,0.0005395077,0.0003015001],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004471733,"about_ca_system_score_gemma":0.0002945567,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001563672,"about_ca_topic_score_gemma":0.0008155598,"domain_scores_codex":[0.9999524,0.000006049302,0.00000130848,0.00001009834,0.0000131294,0.00001697949],"domain_scores_gemma":[0.9998689,0.00006570081,0.0000180416,0.00001132152,0.00002025209,0.00001578836],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002442364,0.00002693061,0.00009369991,0.00002996432,0.000006001362,0.00005659794,0.00002763055,0.00008324946,0.9980776,0.0002605661,0.00002900862,0.001064425],"study_design_scores_gemma":[0.00003833418,0.000293631,0.002196437,0.000004184517,0.00001074633,0.0001019943,0.00004870668,0.001018537,0.9954839,0.0001198942,0.0006773554,0.00000626962],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9943136,0.001283989,0.002013766,0.0000662036,0.00001524573,0.00001958225,0.00008120714,0.00002184642,0.002184575],"genre_scores_gemma":[0.9961952,0.0003959049,0.0005163095,0.00002790467,0.000006418618,0.000009673384,0.00007966269,0.000005947034,0.002763113],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003613856,"threshold_uncertainty_score":0.01208955,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02031774858397259,"score_gpt":0.2832990088136497,"score_spread":0.2629812602296771,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}