{"id":"W4387093555","doi":"10.1021/acscatal.3c03450","title":"Mechanistic Insights into Selective Indium-Catalyzed Coupling of Epoxides and Lactones","year":2023,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; National Science Foundation","keywords":"Chemistry; Cationic polymerization; Catalysis; Selectivity; Indium; Lewis acids and bases; Monomer; Ether; Reaction mechanism; Polymerization; Lactone; Polymer chemistry; Alkyl; Organic chemistry; Combinatorial chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000343987,0.0007111487,0.0003711419,0.0002098527,0.0002277243,0.0006751589,0.0008381499,0.0006296551,0.001950358],"category_scores_gemma":[0.0004411358,0.0003398258,0.0003333417,0.000120506,0.0004842143,0.00114803,0.0003410737,0.0008957512,0.0003280906],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007774435,"about_ca_system_score_gemma":0.0005479314,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001014668,"about_ca_topic_score_gemma":0.00128418,"domain_scores_codex":[0.9999012,0.00001273672,0.000005396811,0.00001581435,0.00002044584,0.0000443648],"domain_scores_gemma":[0.9999305,0.0000327991,0.00001653291,0.000006049584,0.000005686121,0.000008394515],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009080546,0.0007232359,0.004110753,0.001284157,0.0001055399,0.002561614,0.0004113418,0.09775954,0.7527465,0.1201269,0.001232609,0.01802987],"study_design_scores_gemma":[0.0002575806,0.0007938911,0.003308321,0.00008240276,0.0001038415,0.0006856488,0.0004385948,0.4549659,0.5067188,0.02302583,0.00953346,0.00008592269],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9731652,0.001927612,0.01246266,0.0005514683,0.00005516966,0.0000544133,0.0001976105,0.0001434341,0.0114423],"genre_scores_gemma":[0.9963966,0.001070848,0.001729436,0.00005401136,0.000004720117,0.0000232467,0.00006770331,0.00001055429,0.0006427865],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001950358,"threshold_uncertainty_score":0.006524563,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01100904549152563,"score_gpt":0.2412218602318105,"score_spread":0.2302128147402849,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}