{"id":"W4387344984","doi":"10.1002/chem.202302538","title":"An Unusual Macrocyclic Hexamer of an Iso‐Tellurazole <i>N</i>‐Oxide Featuring CTe<sup>…</sup>O Chalcogen Bonds is Formed by κ<sup>6</sup>‐O Complexation to Fe(II) and Ni(II)","year":2023,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Organic Chemistry Cycloaddition Reactions","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chalcogen; Chemistry; Supramolecular chemistry; Aqueous solution; Oxide; Metal; Molecule; Crystallography; Random hexamer; Nickel; Inorganic chemistry; Metal ions in aqueous solution; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006042447,0.0007323433,0.0006406841,0.0001429159,0.001188518,0.0002955492,0.0009790958,0.0002489171,0.003292221],"category_scores_gemma":[0.0002221596,0.0008150876,0.0002088319,0.0007553325,0.0002497462,0.0006479618,0.0005062,0.001236977,0.0001166868],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003028805,"about_ca_system_score_gemma":0.0001602516,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001989218,"about_ca_topic_score_gemma":0.000001103216,"domain_scores_codex":[0.9958583,0.0001037048,0.001203742,0.001011761,0.0008198048,0.001002711],"domain_scores_gemma":[0.9966253,0.00009331656,0.0006534811,0.001038498,0.0003133287,0.001276097],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001050923,0.0003320876,0.0003269799,0.0002527511,0.0001564294,0.0001524109,0.002479154,0.0005173798,0.9596996,0.000001066442,0.03332388,0.002653133],"study_design_scores_gemma":[0.002242054,0.0001266625,0.0005056151,0.0002634971,0.0001437112,0.001895623,0.004312096,0.00793471,0.9338346,0.00003301987,0.04776249,0.0009459383],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.988971,0.0001150325,0.00006562876,0.0006134087,0.00003687336,0.0001310287,0.00106253,0.0003951454,0.008609364],"genre_scores_gemma":[0.9892999,0.0001151358,0.0004613376,0.000276261,0.001078895,0.00001552347,0.001422018,0.0002382744,0.007092687],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02586505,"threshold_uncertainty_score":0.99943,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01381808914092323,"score_gpt":0.2415368867651858,"score_spread":0.2277187976242626,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}