{"id":"W4387345137","doi":"10.1149/2162-8777/acfff4","title":"N-Heterocyclic Carbene Organic Dyes Derived from 2,4,5,6-tetra(9H-Carbazol-9-yl)isophthalonitrile (4CzIPN) Bonded to TiO<sub>2</sub> Surfaces","year":2023,"lang":"en","type":"article","venue":"ECS Journal of Solid State Science and Technology","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Canada First Research Excellence Fund; Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada","keywords":"Cyclic voltammetry; Photoluminescence; Carbene; Materials science; Chromophore; Photochemistry; Tetra; X-ray photoelectron spectroscopy; Infrared spectroscopy; Benzene; Spectroscopy; Polymer chemistry; Chemistry; Electrochemistry; Physical chemistry; Organic chemistry; Medicinal chemistry; Chemical engineering; Electrode; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001053914,0.0004265186,0.0002953012,0.0001599587,0.0001379452,0.0002041506,0.0004586232,0.0003556212,0.001064728],"category_scores_gemma":[0.0001224333,0.0001647766,0.0001751156,0.0001941789,0.0002383364,0.0002189223,0.0002852235,0.0005005033,0.0003906013],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004693446,"about_ca_system_score_gemma":0.000217959,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005558319,"about_ca_topic_score_gemma":0.001745278,"domain_scores_codex":[0.9998522,0.00001714234,0.000005771199,0.00003422684,0.00005916057,0.00003157578],"domain_scores_gemma":[0.9998918,0.00001694096,0.00003906799,0.00001523024,0.0000143381,0.00002266103],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000172666,0.000007829733,0.0000391748,0.00002628628,0.000002525718,0.00002284946,0.000003392475,0.00004968124,0.9988101,0.00005579998,0.00001747397,0.0009477122],"study_design_scores_gemma":[0.000003760834,0.00008810191,0.0007193755,0.000001833052,0.000003928269,0.00007501253,0.000003640366,0.0001808505,0.9980696,0.00001212705,0.000838774,0.000002971418],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9812479,0.002211171,0.0100184,0.00008250918,0.0000621924,0.00007819653,0.0002786988,0.0001461312,0.005874763],"genre_scores_gemma":[0.9853433,0.0009794862,0.01022362,0.00006541853,0.00001275933,0.00003928922,0.0002827667,0.00003131884,0.003022003],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001064728,"threshold_uncertainty_score":0.003561854,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008834969188321228,"score_gpt":0.2447717199358864,"score_spread":0.2359367507475652,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}