{"id":"W4387368691","doi":"10.1016/j.cej.2023.146452","title":"Electrocatalytic regulation of electrochemiluminescence: Mechanisms and sensing strategies","year":2023,"lang":"en","type":"article","venue":"Chemical Engineering Journal","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":25,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Waterloo","funders":"","keywords":"Electrochemiluminescence; Electrocatalyst; Overpotential; Combinatorial chemistry; Nanoclusters; Chemistry; Nanotechnology; Luminophore; Catalysis; Electrochemistry; Carbon nanotube; Biosensor; Detection limit; Materials science; Organic chemistry; Physical chemistry; Electrode","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005441087,0.0004507113,0.0002850884,0.0002967386,0.0001743949,0.001116848,0.001054032,0.0006353802,0.0007778525],"category_scores_gemma":[0.0005730565,0.0002139369,0.0003011169,0.000200007,0.000728032,0.0008548321,0.000377831,0.0009425692,0.0002490147],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006678859,"about_ca_system_score_gemma":0.0001894054,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003463674,"about_ca_topic_score_gemma":0.0003663682,"domain_scores_codex":[0.9997227,0.00004571514,0.00001548964,0.00008324937,0.00007920615,0.00005360557],"domain_scores_gemma":[0.9997832,0.0001008567,0.00003396352,0.00002001031,0.0000435968,0.00001836071],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000628193,0.00005558215,0.0001954107,0.00008085612,0.000008026474,0.00005752119,0.0000605835,0.0001248438,0.9880669,0.002817791,0.0001899669,0.008279766],"study_design_scores_gemma":[0.000008237718,0.00005584713,0.0007216921,0.000007022053,0.000008576956,0.0001559253,0.00005110482,0.003586615,0.9918018,0.001259219,0.002332956,0.00001098033],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8052142,0.02224388,0.1545491,0.003197704,0.0004465954,0.0002192981,0.000304398,0.0009047426,0.01292013],"genre_scores_gemma":[0.9863136,0.002808157,0.007840654,0.0003969066,0.00004142644,0.00006834535,0.0001123727,0.00004246266,0.002376039],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001116848,"threshold_uncertainty_score":0.004845858,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004326574553028927,"score_gpt":0.2231850296760811,"score_spread":0.2188584551230522,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}