{"id":"W4387449858","doi":"10.1002/ange.202312936","title":"A Heterometallic Porphyrin Dimer as a Potential Quantum Gate: Magneto‐Structural Correlations and Spin Coherence Properties","year":2023,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Trinity College","funders":"Institute for Advanced Study, Technische Universität München; H2020 Future and Emerging Technologies; Ministero dell'Università e della Ricerca; Irish Research Council; Science Foundation Ireland","keywords":"Electron paramagnetic resonance; Pulsed EPR; Porphyrin; Dimer; Spin (aerodynamics); Chemistry; Antiferromagnetism; Condensed matter physics; Spins; Exchange interaction; Ferromagnetism; Molecular physics; Chemical physics; Crystallography; Materials science; Physics; Nuclear magnetic resonance; Spin echo; Photochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005712153,0.00008157898,0.000126281,0.00007365656,0.000152785,0.0001990051,0.0001862496,0.0001554551,0.0008849225],"category_scores_gemma":[0.00008023255,0.000077558,0.00003939409,0.00007776276,0.0001606141,0.0001483378,0.0001537776,0.0002427132,0.0001621869],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001191808,"about_ca_system_score_gemma":0.00006173591,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009871997,"about_ca_topic_score_gemma":0.0001173954,"domain_scores_codex":[0.9999616,0.00001020611,0.000001121382,0.00001118727,0.000009600568,0.000006300765],"domain_scores_gemma":[0.9999602,0.000007430047,0.00000707754,0.000008137556,0.000004400038,0.00001274644],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001014091,0.00006984939,0.0002778991,0.00004128379,0.00000905413,0.0001434228,0.00002738134,0.001364804,0.9915302,0.002046163,0.0002131754,0.004175387],"study_design_scores_gemma":[0.00005942941,0.0005180017,0.002345455,0.000006651777,0.00001902156,0.0003271509,0.00003237768,0.06010601,0.9306984,0.00143598,0.004436401,0.00001523037],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9945208,0.0003841669,0.003179094,0.0001200364,0.00001342945,0.00000666998,0.0000272216,0.00004343061,0.00170515],"genre_scores_gemma":[0.9983175,0.0000611282,0.0009714561,0.00001000774,0.000001832074,0.000002481291,0.00001010935,0.000004849758,0.0006206936],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008849225,"threshold_uncertainty_score":0.002960324,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02423053580811423,"score_gpt":0.2533725858234664,"score_spread":0.2291420500153522,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}