{"id":"W4387570378","doi":"10.1002/cctc.202300989","title":"Synthetic Applications of Photochemically Generated Radicals from Protic C(sp<sup>3</sup>)−H Bonds","year":2023,"lang":"en","type":"article","venue":"ChemCatChem","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Radical; Chemistry; Electrophile; Nucleophile; Photochemistry; Reactivity (psychology); Surface modification; Proton; Yield (engineering); Electron transfer; Proton-coupled electron transfer; Organic synthesis; Organic chemistry; Catalysis; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002160372,0.0003470271,0.0001459529,0.000222836,0.0002086615,0.0002876058,0.0002589962,0.0004658257,0.001975959],"category_scores_gemma":[0.0001580221,0.0001139059,0.0002540755,0.0001757674,0.0002585666,0.0003914101,0.0003504825,0.0005984583,0.0004652836],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001625562,"about_ca_system_score_gemma":0.0001334551,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000904592,"about_ca_topic_score_gemma":0.0001635271,"domain_scores_codex":[0.9999282,0.0000123212,0.000003541484,0.00001461132,0.0000218543,0.00001945101],"domain_scores_gemma":[0.9999465,0.00001671553,0.00001376228,0.000005751753,0.000009451986,0.000007894908],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001441697,0.00009797901,0.0002421976,0.001488896,0.00003741606,0.0007046447,0.000146331,0.001152183,0.9003013,0.01706826,0.002234878,0.07638173],"study_design_scores_gemma":[0.00003653741,0.0007076072,0.0004615043,0.00005171337,0.00003341402,0.0008458594,0.00007279678,0.001016844,0.9416257,0.002606161,0.05251934,0.00002254248],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.668,0.1703798,0.06687425,0.002080343,0.002078057,0.0003523277,0.0005021549,0.0005032731,0.08922987],"genre_scores_gemma":[0.9472077,0.0333276,0.01246228,0.0002948825,0.0001848392,0.00006349979,0.0001233872,0.00003761919,0.006298226],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001975959,"threshold_uncertainty_score":0.006610215,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01405498003393568,"score_gpt":0.2525725534671518,"score_spread":0.2385175734332161,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}