{"id":"W4387582130","doi":"10.1055/s-0042-1751495","title":"Boryl Acrylaldehyde: An Elusive Member of the α-Boryl Aldehyde Class of Reagent","year":2023,"lang":"en","type":"article","venue":"Synlett","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Aldehyde; Chemistry; Reagent; Combinatorial chemistry; Aldol reaction; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004126016,0.0001931141,0.000393014,0.0001180593,0.00009948476,0.00001121981,0.0006646473,0.000166035,0.0008948827],"category_scores_gemma":[0.0003487402,0.0001398391,0.0003232184,0.001046329,0.0001703967,0.00007425445,0.0002762596,0.0001691964,0.00008024908],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005828259,"about_ca_system_score_gemma":0.00007832576,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001914472,"about_ca_topic_score_gemma":0.00003911142,"domain_scores_codex":[0.9981865,0.00005588386,0.0004903862,0.0003374614,0.0005794402,0.0003503709],"domain_scores_gemma":[0.9980053,0.0002604911,0.0003484599,0.001176595,0.0001185495,0.00009057649],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001026112,0.000616634,0.01654796,0.0007627204,0.001102853,0.00004149872,0.002834745,0.0002794317,0.8177397,0.002682345,0.05471045,0.1025791],"study_design_scores_gemma":[0.0003012983,0.00001962978,0.005988592,0.00008168736,0.0002004284,0.000004402082,0.001724479,0.0003338192,0.9620658,0.0002907464,0.02876332,0.0002257697],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9280987,0.0002656002,0.0000167719,0.0008720799,0.0001599216,0.0001023443,0.0001660588,0.00009627017,0.07022221],"genre_scores_gemma":[0.9952157,0.00008716873,0.0000543965,0.00009525026,0.0001567922,0.00002422414,0.00003929699,0.00003854556,0.004288631],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1443262,"threshold_uncertainty_score":0.9798337,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01987934977507628,"score_gpt":0.2607532924696748,"score_spread":0.2408739426945986,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}