{"id":"W4387582130","doi":"10.1055/s-0042-1751495","title":"Boryl Acrylaldehyde: An Elusive Member of the α-Boryl Aldehyde Class of Reagent","year":2023,"lang":"en","type":"article","venue":"Synlett","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Aldehyde; Chemistry; Reagent; Combinatorial chemistry; Aldol reaction; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002236148,0.000369623,0.0001386693,0.0001653843,0.0002085901,0.0002235478,0.0003346213,0.0002292084,0.002339402],"category_scores_gemma":[0.0001304109,0.0001259717,0.0001656842,0.00008936646,0.0002332606,0.0004341034,0.0003230214,0.0004992642,0.0009632889],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002288355,"about_ca_system_score_gemma":0.0002172938,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000233089,"about_ca_topic_score_gemma":0.0003497959,"domain_scores_codex":[0.9998741,0.00002368212,0.000008242559,0.0000208914,0.00003885151,0.0000341876],"domain_scores_gemma":[0.9999323,0.000009036231,0.00002025015,0.00001026158,0.00001058788,0.00001753914],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001151055,0.0001179289,0.0003420739,0.0004304848,0.00002962706,0.0004833506,0.0001032569,0.0009660422,0.958266,0.02012851,0.00090059,0.01811697],"study_design_scores_gemma":[0.00003686679,0.0006162634,0.0004554061,0.0000325455,0.00002214172,0.0006513335,0.00003335844,0.001943868,0.9522914,0.001562417,0.04233012,0.00002425649],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.788278,0.01574525,0.1379349,0.002472984,0.0009538978,0.0002312899,0.000363516,0.0009183988,0.05310186],"genre_scores_gemma":[0.9664103,0.004045186,0.02256189,0.0002035424,0.00005901127,0.0000463552,0.0001066306,0.00006945043,0.006497527],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002339402,"threshold_uncertainty_score":0.00782603,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01987934977507628,"score_gpt":0.2607532924696748,"score_spread":0.2408739426945986,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}