{"id":"W4387668558","doi":"10.26434/chemrxiv-2023-1v00g","title":"A Tetrahedral Neptunium(V) Complex","year":2023,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Office of Science; Basic Energy Sciences; Canadian Centre for Applied Research in Cancer Control; University of South Dakota; University of Akron; Georgia Institute of Technology; U.S. Department of Energy; New Mexico State University; National Science Foundation","keywords":"Neptunium; Actinide; Chemistry; Crystallography; Oxidation state; Transuranium element; Uranium; Rietveld refinement; Crystal structure; Inorganic chemistry; Metal; Physical chemistry; Materials science; Organic chemistry; Metallurgy","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004097476,0.0001355578,0.0002047764,0.0001028295,0.000311447,0.0004602171,0.0004680101,0.0003523958,0.001561628],"category_scores_gemma":[0.000143275,0.0001157298,0.00007476548,0.0001480114,0.000180785,0.0002017507,0.0003298636,0.0003660026,0.0003343522],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000492234,"about_ca_system_score_gemma":0.0001860116,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009740559,"about_ca_topic_score_gemma":0.001008529,"domain_scores_codex":[0.9998935,0.000009175112,0.000005954211,0.00003849355,0.00003132242,0.00002140614],"domain_scores_gemma":[0.9999763,0.000002882595,0.000005982201,0.000004084899,0.000002813216,0.000007951286],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001511438,0.00004212539,0.0005448933,0.0001766176,0.00002226386,0.0001966808,0.0001111644,0.001406863,0.9819888,0.006095573,0.00152167,0.007742282],"study_design_scores_gemma":[0.00006587658,0.0003187037,0.001788398,0.00001297152,0.00002276564,0.0008714367,0.0001019704,0.006168811,0.9496893,0.0009452268,0.03998629,0.00002821958],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9806409,0.001067141,0.008091506,0.0003910043,0.00008519466,0.00003508333,0.0004308918,0.000219966,0.009038334],"genre_scores_gemma":[0.9897697,0.0003665584,0.004237514,0.00008951088,0.000006945456,0.00002454318,0.0006499913,0.00003462602,0.004820583],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001561628,"threshold_uncertainty_score":0.005224228,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.09402724860642057,"score_gpt":0.3119145958010074,"score_spread":0.2178873471945868,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}