{"id":"W4387811564","doi":"10.1038/s42005-023-01414-7","title":"X-ray induced Coulomb explosion imaging of transient excited-state structural rearrangements in CS2","year":2023,"lang":"en","type":"article","venue":"Communications Physics","topic":"Laser-Matter Interactions and Applications","field":"Physics and Astronomy","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"Max Planck - University of Ottawa Centre for Extreme and Quantum Photonics; University of Ottawa; National Research Council Canada","funders":"SLAC National Accelerator Laboratory; Chemical Sciences, Geosciences, and Biosciences Division; Horizon 2020; Deutsches Elektronen-Synchrotron; Science and Technology Facilities Council; Basic Energy Sciences; Natural Sciences and Engineering Research Council of Canada; Office of Science; Bundesministerium für Bildung und Forschung; U.S. Department of Energy; CALIPSOplus; European Commission; National Defense Science and Engineering Graduate; Max-Planck-Gesellschaft; Engineering and Physical Sciences Research Council; UK Research and Innovation; University of Southampton; Leverhulme Trust; University of Ottawa","keywords":"Coulomb explosion; Photoexcitation; Excited state; Intersystem crossing; Observable; Photodissociation; Chemical physics; Atomic physics; Adiabatic process; Coulomb; Chemistry; Molecular physics; Ionization; Physics; Photochemistry; Nuclear physics; Ion; Singlet state; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008666609,0.0001173414,0.0001509152,0.0001046042,0.0001809603,0.00003239696,0.0005220257,0.00001292362,0.00006290411],"category_scores_gemma":[0.000002176177,0.0001206402,0.00007740097,0.0007578878,0.00006707774,0.0002458472,0.0001798671,0.0001978719,0.00008612679],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000298927,"about_ca_system_score_gemma":0.00002890526,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000412875,"about_ca_topic_score_gemma":0.00002067864,"domain_scores_codex":[0.9991565,0.00006340427,0.0003243783,0.0001601578,0.0001196081,0.0001759142],"domain_scores_gemma":[0.9985144,0.0000922551,0.0001337465,0.00112182,0.00009920246,0.00003857317],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.00004867761,0.002613586,0.2275949,0.0001256395,0.0003561838,0.000001852042,0.02203245,0.01181523,0.362372,0.06215443,0.01152676,0.2993583],"study_design_scores_gemma":[0.00438345,0.00009224605,0.5391372,0.0007410693,0.0001834636,0.000001345465,0.01138326,0.2565501,0.04361952,0.1144876,0.02779789,0.001622882],"study_design_candidate":"observational","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9909301,0.00001301755,0.003775557,0.000917296,0.00006866882,0.00032086,0.0001563109,0.00006263635,0.003755603],"genre_scores_gemma":[0.9985834,0.00001410034,0.0005561225,0.00003295064,0.00003201274,0.0001834843,0.0004350638,0.00002002353,0.0001428079],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3187525,"threshold_uncertainty_score":0.4919564,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04737440414781197,"score_gpt":0.3354019118972719,"score_spread":0.28802750774946,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}