{"id":"W4388023943","doi":"10.21203/rs.3.rs-3465325/v1","title":"Four-Electron Reduction of Benzene by a Simple Samarium(II)-Alkyl","year":2023,"lang":"en","type":"preprint","venue":"Research Square","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of British Columbia","funders":"MacDiarmid Institute for Advanced Materials and Nanotechnology; Victoria University; Victoria University of Wellington; Royal Society Te Apārangi","keywords":"Benzene; Samarium; Chemistry; Reagent; Aromaticity; Reactivity (psychology); Alkyl; Medicinal chemistry; Photochemistry; Inorganic chemistry; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001426603,0.0001967818,0.0001835,0.0001181497,0.0002077582,0.0001709117,0.0003452112,0.000267274,0.003444033],"category_scores_gemma":[0.0001050335,0.00007664791,0.0001532801,0.0001251779,0.0001067813,0.0001974102,0.0002959117,0.0002320266,0.0008199883],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001985375,"about_ca_system_score_gemma":0.0001388863,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003829116,"about_ca_topic_score_gemma":0.0008445921,"domain_scores_codex":[0.9998965,0.00001776425,0.000004881122,0.00001542337,0.00002381989,0.00004158484],"domain_scores_gemma":[0.999974,0.000005128859,0.000004318105,0.000006611601,0.000002924427,0.000006981125],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002744668,0.00003778836,0.0002233748,0.0001507662,0.00001589053,0.0001766066,0.00008457806,0.0001227158,0.9887311,0.001746704,0.0004393473,0.007996693],"study_design_scores_gemma":[0.00001413489,0.0002925661,0.0007014794,0.000003378172,0.00000955419,0.0001676067,0.00001965451,0.0003616364,0.9913101,0.0001718424,0.006942494,0.000005493536],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9661061,0.001644219,0.01316038,0.0003640926,0.0001422015,0.00003935018,0.0002918948,0.0003039951,0.0179478],"genre_scores_gemma":[0.988434,0.0003970338,0.00265201,0.00004326953,0.00001543123,0.000008499215,0.00015212,0.00001881922,0.008278727],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003444033,"threshold_uncertainty_score":0.01152146,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.08529204441889537,"score_gpt":0.3630053875000033,"score_spread":0.2777133430811079,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}