{"id":"W4388038424","doi":"10.1021/acs.organomet.3c00353","title":"Protonolysis of BH<sub>4</sub><sup>–</sup> Leads to Intermediacy of BH<sub>3</sub>-σ(H<sub>2</sub>) That Evolves H<sub>2</sub> and Furnishes Borane as the Key Reducing Agent","year":2023,"lang":"en","type":"article","venue":"Organometallics","topic":"Hydrogen Storage and Materials","field":"Materials Science","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brandon University","funders":"Brandon University","keywords":"Chemistry; Protonolysis; Hydride; Borohydride; Borane; Intramolecular force; Computational chemistry; Medicinal chemistry; Hydrogen; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.003410831,0.001393565,0.002407027,0.001074818,0.0006774325,0.0006988934,0.001865105,0.0006402609,0.0002669544],"category_scores_gemma":[0.001371154,0.001187611,0.0006735683,0.002677343,0.001112892,0.001218819,0.001693586,0.0005933458,0.001503635],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003281078,"about_ca_system_score_gemma":0.0006047548,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001031995,"about_ca_topic_score_gemma":0.0001014963,"domain_scores_codex":[0.9907684,0.0008637297,0.002410854,0.002072129,0.001920743,0.001964097],"domain_scores_gemma":[0.9940876,0.0006619288,0.001402004,0.002391943,0.0006148877,0.0008416292],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002882529,0.0003481701,0.000294728,0.0008351004,0.0003361014,0.0001324657,0.009133169,0.0005125811,0.978006,0.00009904987,0.001398478,0.008615891],"study_design_scores_gemma":[0.001056341,0.0005673162,0.0009831717,0.000537707,0.0005895786,0.00009564003,0.001615833,0.0001789165,0.9911912,0.0004312417,0.001523628,0.001229408],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9926442,0.0007116046,0.0001539657,0.000825309,0.001213223,0.003302742,0.0004917475,0.0004787398,0.0001784946],"genre_scores_gemma":[0.9944741,0.002769366,0.0002970541,0.00041674,0.0006495481,0.0007728388,0.000205241,0.0003456628,0.00006949877],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01318521,"threshold_uncertainty_score":0.9998815,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01938975237097553,"score_gpt":0.2431197674488067,"score_spread":0.2237300150778311,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}