{"id":"W4388089588","doi":"10.1139/cjc-2023-0148","title":"Multiple verdazyl radicals appended to a triarylamine scaffold","year":2023,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation; British Columbia Knowledge Development Fund; University of Victoria","keywords":"Chemistry; Cyclic voltammetry; Electron paramagnetic resonance; Radical; Photochemistry; Spectroscopy; Hyperfine structure; Unpaired electron; Triphenylamine; Absorbance; Physical chemistry; Electrochemistry; Nuclear magnetic resonance; Organic chemistry; Atomic physics; Electrode","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006639853,0.0001196098,0.0002399966,0.0001727649,0.0001179085,0.0001144665,0.0005754145,0.00007691903,0.006207188],"category_scores_gemma":[0.001233345,0.0001205543,0.00008328375,0.0004052521,0.00007873344,0.0001126454,0.00003396573,0.0001226912,0.0003940876],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001459846,"about_ca_system_score_gemma":0.0009005431,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006434817,"about_ca_topic_score_gemma":0.0009848006,"domain_scores_codex":[0.9986838,0.00003190592,0.0004267159,0.0001664301,0.0002970717,0.0003940472],"domain_scores_gemma":[0.9982403,0.0001702431,0.0001703319,0.0002317659,0.0001701908,0.00101715],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001963299,0.000006778458,0.0003679025,0.00003382964,0.000006787089,0.0002389166,0.0001560198,0.0001662017,0.886478,0.00002117577,0.1111098,0.001394977],"study_design_scores_gemma":[0.001063658,0.00005442591,0.001749089,0.00009426292,0.00001196154,0.0002297737,0.0001895341,0.000207284,0.8306322,0.0005442722,0.1649783,0.0002452656],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9915397,0.000131564,0.0001652689,0.004087636,0.0006301963,0.00008934851,0.00006985872,0.00003312538,0.003253321],"genre_scores_gemma":[0.9955583,0.000003433639,0.0008151872,0.0002406319,0.0004375694,0.000004954207,0.000007439105,0.00001753208,0.002914912],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0558459,"threshold_uncertainty_score":0.9947013,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02027025452065131,"score_gpt":0.2460006934878849,"score_spread":0.2257304389672336,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}