{"id":"W4388163203","doi":"10.1016/j.jqsrt.2023.108819","title":"Synchrotron-based pure rotational spectroscopy of H13COOH","year":2023,"lang":"en","type":"article","venue":"Journal of Quantitative Spectroscopy and Radiative Transfer","topic":"Atmospheric Ozone and Climate","field":"Earth and Planetary Sciences","cited_by":3,"is_retracted":false,"has_abstract":false,"ca_institutions":"Canadian Light Source (Canada)","funders":"Government of Saskatchewan; Western Economic Diversification Canada; Natural Sciences and Engineering Research Council of Canada; Canadian Institutes of Health Research; National Research Council Canada; Canada Foundation for Innovation; University of Saskatchewan; Camille and Henry Dreyfus Foundation","keywords":"Line (geometry); Rotational spectrum; Rotational temperature; Physics; Spectroscopy; Ground state; Rotational transition; Molecular spectroscopy; Atmosphere (unit); Infrared; Synchrotron; Atomic physics; Materials science; Spectral line; Rotational spectroscopy; Optics; Angular momentum; Astronomy; Thermodynamics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005375714,0.0002035997,0.0004861916,0.0001312659,0.0001434611,0.00003245957,0.0001587265,0.00007031436,0.00131207],"category_scores_gemma":[0.00005224692,0.0001518261,0.0001831328,0.0006335829,0.0003201829,0.0003353005,0.000002901325,0.0002841614,0.00004720042],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001248524,"about_ca_system_score_gemma":0.0002206744,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006065283,"about_ca_topic_score_gemma":0.0001042303,"domain_scores_codex":[0.9983122,0.0001686111,0.0005548961,0.0001900354,0.000448053,0.0003262169],"domain_scores_gemma":[0.9987983,0.0005965029,0.0002025121,0.00007908946,0.0001720976,0.0001515271],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"observational","study_design_gemma":"observational","study_design_scores_codex":[0.006147881,0.000441817,0.693279,0.0005568768,0.001416339,0.0004063592,0.01101762,0.06570101,0.1870363,0.02574432,0.003290706,0.00496183],"study_design_scores_gemma":[0.002937876,0.005744096,0.8772142,0.0001957058,0.000193214,0.00003165498,0.00343207,0.02260764,0.07903023,0.00765598,0.0005230565,0.0004343087],"study_design_candidate":"observational","study_design_consensus":"observational","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9760152,0.001505772,0.01967911,0.0008786205,0.0002245195,0.0001745085,0.0001793876,0.0000188965,0.001324025],"genre_scores_gemma":[0.985015,0.0009145621,0.01377668,0.0001228994,0.0001040904,9.751492e-7,0.00002732016,0.000008774207,0.00002968436],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1839352,"threshold_uncertainty_score":0.9996009,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02065997947273798,"score_gpt":0.2785332307027111,"score_spread":0.2578732512299732,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}