{"id":"W4388408566","doi":"10.1002/chem.202302925","title":"Rhodium‐Mediated Dehydrogenation of Hydroboranes and Group 14 Compounds: Base‐Stabilized Silylene and Germylene Complexes vs. Transmetalation","year":2023,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"Natural Sciences and Engineering Research Council of Canada; University of Lethbridge","keywords":"Chemistry; Transmetalation; Silylene; Dehydrogenation; Pincer movement; Rhodium; Medicinal chemistry; Pinacol; Pincer ligand; Synthon; Yield (engineering); Hydroboration; Ligand (biochemistry); Catalysis; Stereochemistry; Organic chemistry; Silicon; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001820056,0.0005713985,0.0002844333,0.0001609861,0.000121115,0.0002410999,0.0003859681,0.0002910619,0.002402205],"category_scores_gemma":[0.0001698549,0.0002190106,0.0002205456,0.000122885,0.0002109193,0.0003021807,0.0003071317,0.000407578,0.0007546479],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000337649,"about_ca_system_score_gemma":0.0001884146,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004786541,"about_ca_topic_score_gemma":0.0009186972,"domain_scores_codex":[0.9998531,0.00002169439,0.000008131658,0.00002698474,0.00003169939,0.00005837789],"domain_scores_gemma":[0.9999307,0.00001011999,0.00001985082,0.00001092244,0.000007600743,0.00002068624],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001456703,0.00002710974,0.00006108546,0.00009245894,0.00001105183,0.0000794718,0.00005107679,0.000185171,0.9974959,0.0002972606,0.00008459697,0.001469058],"study_design_scores_gemma":[0.00001271399,0.0001429031,0.000215392,0.000002027339,0.000004645284,0.00003327835,0.000007968346,0.0002403506,0.9984567,0.00001114714,0.0008685758,0.000004292013],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9919844,0.0006282899,0.001481993,0.00006472316,0.00002920706,0.00005403374,0.000137297,0.0001518489,0.005468314],"genre_scores_gemma":[0.9963453,0.0003000467,0.0009239431,0.00002085284,0.000004446352,0.00001443013,0.00009768579,0.00003874956,0.00225453],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002402205,"threshold_uncertainty_score":0.008036196,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01448359863099398,"score_gpt":0.2164114622946792,"score_spread":0.2019278636636852,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}