{"id":"W4388452723","doi":"10.1038/s41467-023-42938-4","title":"Low-temperature hydroformylation of ethylene by phosphorous stabilized Rh sites in a one-pot synthesized Rh-(O)-P-MFI zeolite","year":2023,"lang":"en","type":"article","venue":"Nature Communications","topic":"Catalysis and Oxidation Reactions","field":"Chemical Engineering","cited_by":50,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Light Source (Canada)","funders":"Argonne National Laboratory; China Scholarship Council; European Commission; Generalitat Valenciana; Canadian Light Source; Office of Science; Ministerio de Ciencia, Innovación y Universidades; U.S. Department of Energy","keywords":"Hydroformylation; Ethylene; Zeolite; Catalysis; Selectivity; Chemistry; Hydroxide; Inorganic chemistry; Phosphate; Rhodium; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003912944,0.0001954358,0.0003746486,0.0003058287,0.0001677534,0.00003503527,0.0007151127,0.0004904954,0.0001123698],"category_scores_gemma":[0.0008376935,0.0002022382,0.000163874,0.001846296,0.00008710822,0.0002267107,0.0002189272,0.001171601,0.00005627989],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001450572,"about_ca_system_score_gemma":0.00005110709,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001201817,"about_ca_topic_score_gemma":0.0005777886,"domain_scores_codex":[0.9985009,0.00009642434,0.0005749933,0.0002651658,0.0003008958,0.0002616647],"domain_scores_gemma":[0.9969278,0.0009590646,0.0001873271,0.001644763,0.0001994295,0.00008161528],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002974431,0.0002913495,0.0007793052,0.00004420223,0.00006729732,3.768079e-7,0.0005381136,0.0005153781,0.9921718,0.002619347,0.002234146,0.000708933],"study_design_scores_gemma":[0.001649114,0.00002652421,0.01066148,0.0002515827,0.0001213521,0.000003092504,0.0005629291,0.02691219,0.9325304,0.0004557437,0.02626603,0.000559535],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9911209,0.00330476,0.00006565567,0.002946986,0.0000783103,0.0003978852,0.0002619,0.0003272707,0.001496369],"genre_scores_gemma":[0.9940076,0.00160833,0.001019908,0.0000871027,0.00002497879,0.0001307334,0.002492401,0.00003863728,0.0005903397],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05964139,"threshold_uncertainty_score":0.8247036,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01721503511177544,"score_gpt":0.2737433894712764,"score_spread":0.2565283543595009,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}