{"id":"W4388518213","doi":"10.1021/acs.organomet.3c00312","title":"[(NHC)Pd(allyl)Cl] Precatalysts in The Hiyama Reaction of Aryl Chlorides with Aryl Trimethoxysilanes: A Study in Side Reactions","year":2023,"lang":"en","type":"article","venue":"Organometallics","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Trent University","funders":"Natural Sciences and Engineering Research Council of Canada; Trent University","keywords":"Chemistry; Carbene; Aryl; IMes; Steric effects; Palladium; Medicinal chemistry; Catalysis; Organic chemistry; Fluoride; Alkyl","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001805651,0.0002440959,0.0001823626,0.0001212394,0.00008983751,0.0002268382,0.0002698447,0.00033033,0.000602103],"category_scores_gemma":[0.0002364113,0.0001613035,0.0001445317,0.00008813559,0.0001706675,0.000218585,0.0001590831,0.0003682128,0.0002574977],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000158974,"about_ca_system_score_gemma":0.0001319151,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005102324,"about_ca_topic_score_gemma":0.001133457,"domain_scores_codex":[0.99988,0.00001717717,0.00000916911,0.00002210237,0.00003961091,0.0000319575],"domain_scores_gemma":[0.9998609,0.00003679952,0.0000417237,0.0000149626,0.00002649357,0.00001918226],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004759857,0.00001042937,0.00009976389,0.00003868892,0.000005299393,0.00005250183,0.00001777528,0.00005190254,0.9982377,0.0000504181,0.00001295998,0.001374786],"study_design_scores_gemma":[0.000003232897,0.0001438973,0.000471617,0.000001811861,0.000007317895,0.00007738484,0.000007126995,0.0001445807,0.9986705,0.000007751945,0.0004632479,0.000001553525],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9939575,0.001983404,0.001853071,0.00004372976,0.00001022113,0.00002009014,0.00004936595,0.00005519979,0.002027305],"genre_scores_gemma":[0.9961861,0.001002781,0.001289138,0.00001983301,0.000004304961,0.000009097659,0.00007443959,0.00000972706,0.00140468],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000602103,"threshold_uncertainty_score":0.00201422,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03005196513431705,"score_gpt":0.2935609792827032,"score_spread":0.2635090141483861,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}