{"id":"W4388518213","doi":"10.1021/acs.organomet.3c00312","title":"[(NHC)Pd(allyl)Cl] Precatalysts in The Hiyama Reaction of Aryl Chlorides with Aryl Trimethoxysilanes: A Study in Side Reactions","year":2023,"lang":"en","type":"article","venue":"Organometallics","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Trent University","funders":"Natural Sciences and Engineering Research Council of Canada; Trent University","keywords":"Chemistry; Carbene; Aryl; IMes; Steric effects; Palladium; Medicinal chemistry; Catalysis; Organic chemistry; Fluoride; Alkyl","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.001035495,0.0003296355,0.0005185569,0.0005032708,0.0001357656,0.00008546234,0.0005039173,0.0001674624,0.00009683533],"category_scores_gemma":[0.0004257459,0.0002663248,0.0001252763,0.003467875,0.0001492254,0.0003294491,0.0001034449,0.0006665835,0.0001014059],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002812728,"about_ca_system_score_gemma":0.0002163366,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001990984,"about_ca_topic_score_gemma":0.003407593,"domain_scores_codex":[0.9975533,0.000003720068,0.0008095611,0.0005997139,0.0005880967,0.000445634],"domain_scores_gemma":[0.9974844,0.0008140997,0.0003567585,0.00115823,0.0001102953,0.00007622593],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001993208,0.001609438,0.051508,0.000211302,0.0002068907,0.0001494877,0.004868746,0.0005721431,0.939801,0.00007508738,0.00003901363,0.0007595183],"study_design_scores_gemma":[0.00317845,0.0001963773,0.4377934,0.0003394388,0.000406663,0.0002174647,0.03671569,0.0004416228,0.5185506,0.0003895341,0.001045623,0.0007251552],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9981011,0.00005068778,0.000006374302,0.0002457506,0.0001067891,0.000482905,0.00004085368,0.0001890816,0.0007764786],"genre_scores_gemma":[0.9979477,0.00008714735,0.00002402933,0.000008887542,0.0001072794,0.0001969957,0.000262121,0.00007322518,0.001292643],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4212505,"threshold_uncertainty_score":0.9999789,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03005196513431705,"score_gpt":0.2935609792827032,"score_spread":0.2635090141483861,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}