{"id":"W4388592892","doi":"10.1002/chem.202302950","title":"Synthesis of π‐Conjugated Chiral Aza/Boracyclophanes with a <i>meta</i> and <i>para</i> Substitution","year":2023,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Beijing Institute of Technology; Natural Science Foundation of Beijing Municipality; Queen's University; National Natural Science Foundation of China","keywords":"Racemization; Conjugated system; Chemistry; Substitution (logic); Ring (chemistry); Enantioselective synthesis; Stereochemistry; Combinatorial chemistry; Catalysis; Organic chemistry; Polymer","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006681859,0.0002018962,0.00019917,0.0001046647,0.000120775,0.000199395,0.0001185315,0.0001188497,0.0008007533],"category_scores_gemma":[0.00009667412,0.00009649222,0.00008467439,0.00009614559,0.00009897872,0.0001475123,0.0001320041,0.0002067069,0.0002875093],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001841363,"about_ca_system_score_gemma":0.0001692625,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003982368,"about_ca_topic_score_gemma":0.00125362,"domain_scores_codex":[0.9999545,0.000006314212,0.000004573548,0.00001529793,0.000008969197,0.00001042347],"domain_scores_gemma":[0.9999536,0.000006941456,0.00001297993,0.00000525054,0.000005182021,0.0000160486],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000527234,0.00001471814,0.0001491597,0.00007191564,0.000005524451,0.0000866719,0.0000232278,0.0002664999,0.9926765,0.0004211146,0.00005775306,0.006174013],"study_design_scores_gemma":[0.00002201122,0.0003069005,0.001564082,0.00000807588,0.00001517153,0.0002451126,0.00001738365,0.001011364,0.9901805,0.00008615988,0.006532343,0.00001087473],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9853457,0.002604036,0.005114675,0.00006049778,0.00004798171,0.00004951619,0.0003151852,0.00006312662,0.006399332],"genre_scores_gemma":[0.9844973,0.001544431,0.01106497,0.00003955485,0.000008451047,0.00003710579,0.000213567,0.00001772914,0.002576922],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008007533,"threshold_uncertainty_score":0.002678812,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02685218768932127,"score_gpt":0.2140411129032614,"score_spread":0.1871889252139402,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}