{"id":"W4388847269","doi":"10.1002/chem.202302714","title":"Electron‐Triggered Imine Coupling: Synthesis and Characterization of Three Redox States (0,–1,–2) of a Ni(N<sub>2</sub>S<sub>2</sub>) Complex","year":2023,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Ministero dello Sviluppo Economico; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Ontario Ministry of Economic Development and Innovation; University of Ottawa","keywords":"Imine; Delocalized electron; Chemistry; Electron paramagnetic resonance; Redox; Ligand (biochemistry); Crystallography; Electrochemistry; Photochemistry; Cyclic voltammetry; Medicinal chemistry; Inorganic chemistry; Physical chemistry; Nuclear magnetic resonance; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001399733,0.0002435557,0.0001513098,0.000122747,0.0001034915,0.0002546255,0.0003089816,0.0002735122,0.001049852],"category_scores_gemma":[0.0002803283,0.0001208107,0.00008104589,0.0001077508,0.0001802671,0.0001673105,0.0001442669,0.0002390494,0.0001755704],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00023541,"about_ca_system_score_gemma":0.00008597212,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004061801,"about_ca_topic_score_gemma":0.0008028299,"domain_scores_codex":[0.999898,0.00002001432,0.000006089627,0.00002954131,0.00003030254,0.00001616672],"domain_scores_gemma":[0.9999125,0.00001336303,0.00002527366,0.00001186372,0.00002130659,0.00001563519],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005974893,0.000009604212,0.00008614199,0.00002039644,0.000003772717,0.0000143675,0.00002660098,0.0000464726,0.9988789,0.00004798261,0.00001742831,0.0007884949],"study_design_scores_gemma":[0.000003317594,0.00005712422,0.0004793087,9.435308e-7,0.000002922043,0.00002033318,0.000008197745,0.0003357452,0.9986767,0.000009196892,0.000404481,0.000001666134],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9963397,0.0002012851,0.002198434,0.00002304271,0.000007224173,0.00001470839,0.00008899959,0.0000462319,0.001080382],"genre_scores_gemma":[0.9967168,0.00009930969,0.001540347,0.00001500156,0.000002650204,0.00001145405,0.0001266317,0.00001424458,0.001473588],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001049852,"threshold_uncertainty_score":0.003512084,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01842730242059296,"score_gpt":0.20842096980034,"score_spread":0.1899936673797471,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}