{"id":"W4388850696","doi":"10.1055/s-0043-1763621","title":"Asymmetric Cu(I)-Catalyzed Conjugate Borylation of α,β-Unsaturated Acyl Silanes","year":2023,"lang":"en","type":"article","venue":"Synlett","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; University of Toronto; Canada Research Chairs; Government of Ontario; Canada Foundation for Innovation; Ontario Research Foundation; Alfred P. Sloan Foundation","keywords":"Chemistry; Silanes; Borylation; Alkyl; Catalysis; Conjugate; Aryl; Organic chemistry; Yield (engineering); Silylation; Combinatorial chemistry; Silane","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000132784,0.000212161,0.0002963539,0.0001471497,0.00007256087,0.00002954549,0.0002822854,0.000231503,0.001602736],"category_scores_gemma":[0.0002674721,0.0002103128,0.000101927,0.001076983,0.00009085015,0.00009866387,0.00008563458,0.0002154669,0.000606003],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004840391,"about_ca_system_score_gemma":0.00007109541,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004614841,"about_ca_topic_score_gemma":0.000004914515,"domain_scores_codex":[0.9986216,0.00001456965,0.0003888831,0.000332818,0.0003080258,0.000334117],"domain_scores_gemma":[0.9989748,0.0001520697,0.0001872462,0.0004734076,0.0001012741,0.0001111984],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002732062,0.00003798922,0.004596025,0.0002545704,0.00004822333,0.00001932992,0.00008741363,0.000007096829,0.9876062,0.00004455307,0.005138591,0.002132731],"study_design_scores_gemma":[0.0006502604,0.000006557205,0.003709865,0.00004051524,0.00003326577,0.000008688949,0.0001354592,0.0002633261,0.9917727,0.00006445287,0.003086031,0.0002289446],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9871368,0.0002774649,0.000004347525,0.0004367854,0.0001562369,0.00005900614,0.00008817339,0.0004864881,0.01135472],"genre_scores_gemma":[0.9969749,0.0001076146,0.00003177857,0.00006044188,0.0001775993,0.000008450565,0.0004455349,0.00004619057,0.002147515],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009838093,"threshold_uncertainty_score":0.99931,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0126722835608803,"score_gpt":0.2424230596418891,"score_spread":0.2297507760810088,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}