{"id":"W4388862089","doi":"10.1002/marc.202300563","title":"Sulfur Free Crosslinking of EPDM Composites via Silane Grafting and Silica Incorporation","year":2023,"lang":"en","type":"article","venue":"Macromolecular Rapid Communications","topic":"biodegradable polymer synthesis and properties","field":"Materials Science","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Air Canada; University of Waterloo","funders":"Ontario Centre of Innovation","keywords":"Materials science; Silane; Composite material; Ultimate tensile strength; Vulcanization; EPDM rubber; Natural rubber; Grafting; Ethylene propylene rubber; Fourier transform infrared spectroscopy; Precipitated silica; Copolymer; Chemical engineering; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006094687,0.000132498,0.0002127076,0.0001122815,0.0005856049,0.0001202187,0.0009410348,0.00006715555,0.00005346931],"category_scores_gemma":[0.0001034008,0.0001232016,0.00005500625,0.0003677798,0.0003851629,0.0001257972,0.0008508693,0.0001117852,0.00004418792],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001192949,"about_ca_system_score_gemma":0.00002857037,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004152698,"about_ca_topic_score_gemma":0.0000885768,"domain_scores_codex":[0.9987403,0.0002776213,0.0003737837,0.0002112978,0.0001894331,0.0002075306],"domain_scores_gemma":[0.9978966,0.0002429154,0.0001941633,0.001529829,0.00009191105,0.00004458645],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000008881385,0.00003730963,0.0003406082,0.00003085734,0.00001391261,0.000001629149,0.0006056385,0.000008932902,0.9751243,0.001095613,0.00006648678,0.02266581],"study_design_scores_gemma":[0.0001998387,0.00004990708,0.0009091736,0.00005086163,0.00003304448,0.00001305346,0.0001204082,0.008068449,0.9864635,0.002067342,0.001849769,0.000174649],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.955772,0.03302612,0.004124335,0.004486117,0.0001081986,0.0002978323,0.0001052797,0.0003269172,0.001753194],"genre_scores_gemma":[0.9912927,0.0004607652,0.007966915,0.00008999732,0.00001111556,0.00003985238,0.00007587364,0.00002037482,0.00004237615],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03552072,"threshold_uncertainty_score":0.5024017,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02999265973332134,"score_gpt":0.2495777627831713,"score_spread":0.21958510304985,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}