{"id":"W4389060490","doi":"10.1016/j.jfluchem.2023.110232","title":"Synthesis and hydrolysis of aryl fluoroglycosides","year":2023,"lang":"en","type":"article","venue":"Journal of Fluorine Chemistry","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":6,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université de Montréal; Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation; Fonds de recherche du Québec – Nature et technologies; Université Laval","keywords":"Chemistry; Anomer; Hydrolysis; Aryl; Galactosides; Reaction rate constant; Organic chemistry; Catalysis; Acid hydrolysis; Carbohydrate; Glycoside; Medicinal chemistry; Alkyl; Kinetics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002913242,0.0006556679,0.000285826,0.000340418,0.0002797265,0.0001712509,0.0002862511,0.000404191,0.002775091],"category_scores_gemma":[0.0002355399,0.0001625368,0.0003021213,0.0004553085,0.0001590473,0.000281693,0.0004044661,0.0006317213,0.001485159],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002667196,"about_ca_system_score_gemma":0.0004758259,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007248175,"about_ca_topic_score_gemma":0.0009488694,"domain_scores_codex":[0.9997516,0.0000302257,0.00002265269,0.00002821935,0.00004902856,0.0001182395],"domain_scores_gemma":[0.9998899,0.00001634111,0.00001679306,0.00001792067,0.0000247414,0.00003432162],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004212553,0.00009342904,0.0002403507,0.0001571725,0.00001680052,0.0005092529,0.0001213196,0.0006709925,0.9778497,0.001224014,0.0003406864,0.01835508],"study_design_scores_gemma":[0.00002537412,0.0003395549,0.000583017,0.000008763936,0.000009677812,0.0001486706,0.00002531669,0.0003237459,0.992583,0.0001238507,0.005819383,0.000009529654],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9044738,0.003262569,0.06483909,0.0004017541,0.0002317956,0.0005284863,0.002174916,0.0003886763,0.02369891],"genre_scores_gemma":[0.9667128,0.003202027,0.01680925,0.0001210507,0.00003220146,0.0001789222,0.001967407,0.00007315043,0.0109032],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002775091,"threshold_uncertainty_score":0.009283662,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05707141205099058,"score_gpt":0.3780291386046761,"score_spread":0.3209577265536855,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}