{"id":"W4389122271","doi":"10.1002/anie.202317063","title":"Click to Self‐immolation: A “Click” Functionalization Strategy towards Triggerable Self‐Immolative Homopolymers and Block Copolymers","year":2023,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Copolymer; Click chemistry; Isocyanate; Surface modification; Amphiphile; Polymer; Depolymerization; Self-healing hydrogels; Materials science; ROMP; Chemistry; Combinatorial chemistry; Nanotechnology; Polymer chemistry; Polymerization; Organic chemistry; Metathesis; Polyurethane","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003351877,0.0006176114,0.000234346,0.0002276507,0.0001245437,0.0002191213,0.0002813111,0.0003673923,0.001101406],"category_scores_gemma":[0.0001958038,0.0002054147,0.0002684155,0.0001549861,0.0002975573,0.0004356575,0.0003350916,0.0004776467,0.0004353576],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001972523,"about_ca_system_score_gemma":0.0002723498,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001769063,"about_ca_topic_score_gemma":0.0002813468,"domain_scores_codex":[0.9997881,0.00003588703,0.00001809521,0.00005593005,0.00005762247,0.00004435656],"domain_scores_gemma":[0.9998964,0.00002295018,0.00003424413,0.00001029313,0.00001091981,0.00002511361],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004049135,0.00003341682,0.00004735075,0.00005174311,0.000005679106,0.00007919917,0.00001662865,0.0001260629,0.9961334,0.0004305785,0.0001083836,0.002927098],"study_design_scores_gemma":[0.000006828698,0.0001295168,0.0001824006,0.000001561423,0.00000391365,0.0001120292,0.00000218235,0.0005411546,0.9974971,0.0000246826,0.001492784,0.000005785406],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9220147,0.003230804,0.06617958,0.0003914042,0.0001782524,0.000258646,0.0004955911,0.001030093,0.006221059],"genre_scores_gemma":[0.965308,0.002023564,0.02751668,0.0002316669,0.00005286182,0.0001302434,0.0003500322,0.00008259677,0.004304451],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001101406,"threshold_uncertainty_score":0.00368458,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0150687399021514,"score_gpt":0.2627305525032333,"score_spread":0.2476618126010819,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}