{"id":"W4389140612","doi":"10.1039/d3ob01819a","title":"Restricted rotation and tunable fluorescence in atropisomeric naphthyl pyridine chromophores","year":2023,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Axial and Atropisomeric Chirality Synthesis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Chromophore; Fluorescence; Pyridine; Photochemistry; Organic chemistry; Optics; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001423539,0.0002552825,0.0001347381,0.0001163481,0.00007804142,0.0001728619,0.0002458779,0.0001607531,0.001356293],"category_scores_gemma":[0.0002297217,0.0001128782,0.00009880237,0.0001150384,0.0002796102,0.0002490831,0.0001826283,0.0004607941,0.0003588899],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000264854,"about_ca_system_score_gemma":0.0001435947,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002974212,"about_ca_topic_score_gemma":0.0005361905,"domain_scores_codex":[0.9998776,0.00002439254,0.000005401272,0.00003308863,0.00003618768,0.00002338815],"domain_scores_gemma":[0.9998829,0.00003305761,0.00003857263,0.00001701467,0.00001239149,0.00001592641],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000270961,0.000005851147,0.00002931805,0.00002108597,0.000001067095,0.0000252497,0.00001237905,0.00006480229,0.9981157,0.0003119151,0.00001886036,0.001366669],"study_design_scores_gemma":[0.000004234029,0.00004406746,0.0002876512,0.000001468951,0.000001578617,0.00005108278,0.000004328356,0.0003754811,0.9987038,0.00004000623,0.0004840304,0.000002236967],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9850596,0.0009010963,0.008738871,0.00007305611,0.00001342083,0.00002127721,0.0001525086,0.0001062018,0.004933999],"genre_scores_gemma":[0.9929079,0.0005538979,0.004596043,0.00002738144,0.000006560332,0.00002380393,0.00009516926,0.00002126926,0.001767994],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001356293,"threshold_uncertainty_score":0.004537284,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006921370244093237,"score_gpt":0.2107874794997861,"score_spread":0.2038661092556929,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}