{"id":"W4389298459","doi":"10.1039/d3cc04624a","title":"Divergent process for the catalytic decarboxylative thiocyanation and isothiocyanation of carboxylic acids promoted by visible light","year":2023,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"Fonds de recherche du Québec – Nature et technologies; Horizon 2020 Framework Programme; Région Normandie; Institut Carnot Santé Animale; Canada Foundation for Innovation; Université de Rouen; Centre National de la Recherche Scientifique; Agence Nationale de la Recherche; Natural Sciences and Engineering Research Council of Canada; European Regional Development Fund; Centre in Green Chemistry and Catalysis; European Commission; Indian National Science Academy","keywords":"Catalysis; Decarboxylation; Visible spectrum; Chemistry; Carboxylic acid; Alkyl; Process (computing); Photochemistry; Organic chemistry; Materials science; Computer science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004114731,0.0006694471,0.0002924365,0.0002724116,0.0001909894,0.0004116956,0.0004690746,0.0004218173,0.0009741975],"category_scores_gemma":[0.000342986,0.0001783198,0.0002405438,0.0002865236,0.0004567008,0.0004040888,0.0005458932,0.0009771627,0.0004537327],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003512013,"about_ca_system_score_gemma":0.0005223567,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003427872,"about_ca_topic_score_gemma":0.0004184021,"domain_scores_codex":[0.999754,0.00003059989,0.00001364521,0.00009340529,0.00005083959,0.00005748428],"domain_scores_gemma":[0.9998578,0.00002258458,0.00003291114,0.00003633123,0.00002170198,0.00002872532],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001132949,0.00004733526,0.0001050355,0.00008478239,0.00001177652,0.0001348873,0.00007020091,0.0001636344,0.9897691,0.002958326,0.0001414969,0.006400138],"study_design_scores_gemma":[0.00001737486,0.0001199069,0.0001907428,0.000003265106,0.000006404863,0.0001541282,0.00001077102,0.0007915315,0.995943,0.0002205432,0.002531672,0.00001067466],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8465977,0.002170542,0.1359381,0.0004658118,0.0004925143,0.0004301552,0.000375815,0.0008347426,0.01269472],"genre_scores_gemma":[0.9720536,0.0007831176,0.02315499,0.00006285123,0.00002743346,0.0001154828,0.0001966398,0.0000699051,0.00353605],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009741975,"threshold_uncertainty_score":0.003259063,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03807942432247984,"score_gpt":0.3192754028043133,"score_spread":0.2811959784818334,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}