{"id":"W4389298459","doi":"10.1039/d3cc04624a","title":"Divergent process for the catalytic decarboxylative thiocyanation and isothiocyanation of carboxylic acids promoted by visible light","year":2023,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"Fonds de recherche du Québec – Nature et technologies; Horizon 2020 Framework Programme; Région Normandie; Institut Carnot Santé Animale; Canada Foundation for Innovation; Université de Rouen; Centre National de la Recherche Scientifique; Agence Nationale de la Recherche; Natural Sciences and Engineering Research Council of Canada; European Regional Development Fund; Centre in Green Chemistry and Catalysis; European Commission; Indian National Science Academy","keywords":"Catalysis; Decarboxylation; Visible spectrum; Chemistry; Carboxylic acid; Alkyl; Process (computing); Photochemistry; Organic chemistry; Materials science; Computer science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003054912,0.0001520992,0.0001903171,0.00008121558,0.0002420628,0.00002614767,0.0008902881,0.000152874,0.00001984942],"category_scores_gemma":[0.0008453805,0.0001268979,0.00007549316,0.0005171301,0.0002316347,0.0001093251,0.0002700694,0.0002050696,0.000003447682],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009633197,"about_ca_system_score_gemma":0.00006323246,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003874222,"about_ca_topic_score_gemma":0.000009914224,"domain_scores_codex":[0.9989714,0.0000320134,0.0003439342,0.0002372224,0.0002292002,0.0001862293],"domain_scores_gemma":[0.9971146,0.001193983,0.0002019517,0.001137673,0.0002947647,0.00005705731],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001766243,0.0001059921,0.0003435538,0.0001381378,0.00007495044,5.229979e-8,0.001024915,0.000002268752,0.9933267,0.0007778616,0.001012461,0.003175416],"study_design_scores_gemma":[0.0002464519,0.00001187221,0.00009076419,0.00006607655,0.00008912986,7.150416e-7,0.0004831954,0.009322723,0.9856173,0.001960978,0.001970792,0.0001400096],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9787751,0.001860802,0.0009690455,0.008485067,0.00002733933,0.001023989,0.0002835362,0.0006747019,0.007900449],"genre_scores_gemma":[0.9978098,0.0003555424,0.0004346849,0.00003111221,0.00001799888,0.000739835,0.0004537703,0.00003076518,0.0001264648],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01903475,"threshold_uncertainty_score":0.5174748,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03807942432247984,"score_gpt":0.3192754028043133,"score_spread":0.2811959784818334,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}