{"id":"W4389342568","doi":"10.1039/d3qm01076g","title":"Breaking scaling relations in nitrogen reduction with asymmetrical heterobimetallic FeCo sites to boost ammonia synthesis","year":2023,"lang":"en","type":"article","venue":"Materials Chemistry Frontiers","topic":"Ammonia Synthesis and Nitrogen Reduction","field":"Chemical Engineering","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Institut National de la Recherche Scientifique","funders":"Natural Science Foundation of Jiangsu Province for Distinguished Young Scholars; National Natural Science Foundation of China","keywords":"Dimer; Scaling; Materials science; Reduction (mathematics); Ammonia; Nitrogen; Ammonia production; Chemistry; Mathematics; Geometry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001126937,0.0001483921,0.000105048,0.0001525769,0.00018623,0.0002735091,0.000270037,0.0002498685,0.002631041],"category_scores_gemma":[0.0003089316,0.000131752,0.00006249099,0.00007170741,0.0003353605,0.0004078685,0.0002369586,0.0002559864,0.0002742431],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002985041,"about_ca_system_score_gemma":0.00009786693,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003034973,"about_ca_topic_score_gemma":0.0007431992,"domain_scores_codex":[0.999928,0.000007791125,0.000002837507,0.00001498537,0.00002951634,0.00001676733],"domain_scores_gemma":[0.9999245,0.00002433206,0.00001573374,0.00001149769,0.00001528598,0.000008584296],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001061984,0.00007956932,0.0004614506,0.0001569336,0.000008311699,0.0002166211,0.0001004046,0.004838518,0.9021479,0.07344521,0.001105436,0.01733358],"study_design_scores_gemma":[0.00005221421,0.00032739,0.003572462,0.0000410348,0.00001335098,0.0003421131,0.000171452,0.103086,0.8116303,0.06447627,0.01624849,0.0000388699],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9396787,0.00131269,0.01800491,0.0003713156,0.0001201553,0.00001915191,0.00004856709,0.0001575137,0.04028702],"genre_scores_gemma":[0.9956071,0.0002285858,0.002302251,0.00003578799,0.00001060885,0.00001498887,0.00001953581,0.00002015381,0.001761029],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002631041,"threshold_uncertainty_score":0.008801699,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0106457240550023,"score_gpt":0.2126431371034611,"score_spread":0.2019974130484588,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}