{"id":"W4389437390","doi":"10.1039/d3dt03506a","title":"The impact of Lewis acid variation on reactions with di-<i>tert</i>-butyl diazo diesters","year":2023,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Science Foundation of Ningbo; Natural Sciences and Engineering Research Council of Canada; Ningbo University; Deutsche Forschungsgemeinschaft","keywords":"Diazo; Lewis acids and bases; Steric effects; Chemistry; Bicyclic molecule; Medicinal chemistry; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002838888,0.0003597456,0.0002085784,0.0000982417,0.0001485677,0.0003686459,0.0002900552,0.000297413,0.003033062],"category_scores_gemma":[0.0004913276,0.0001424851,0.0001299754,0.0001234969,0.0002690684,0.0003440036,0.0001903795,0.0002767504,0.0004727039],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001870898,"about_ca_system_score_gemma":0.000203804,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009989628,"about_ca_topic_score_gemma":0.001391631,"domain_scores_codex":[0.9998131,0.00003115424,0.00001194325,0.0000337365,0.00003757127,0.00007255738],"domain_scores_gemma":[0.9998153,0.00008156534,0.00003263063,0.00001556001,0.00002358363,0.00003138117],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001799289,0.00005940248,0.0005232109,0.0001095144,0.00002624396,0.0001647963,0.0000785642,0.0009656303,0.9919152,0.0003600046,0.0001297686,0.003868324],"study_design_scores_gemma":[0.00002523413,0.0004205069,0.0008001633,0.000004627705,0.00001228833,0.00003655511,0.00003911172,0.001095817,0.9967036,0.00007457064,0.0007784607,0.000009290983],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961552,0.0003782156,0.0004487863,0.0000321409,0.00002370697,0.00001562241,0.0001834762,0.00002831217,0.002734517],"genre_scores_gemma":[0.9985436,0.0002918295,0.0002596192,0.00001699921,0.000003251591,0.000006700826,0.0001460162,0.00001397926,0.0007180272],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003033062,"threshold_uncertainty_score":0.01014662,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01131402397160721,"score_gpt":0.2488060022629728,"score_spread":0.2374919782913656,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}