{"id":"W4389485142","doi":"10.1002/cphc.202300828","title":"Cucurbit[6]uril Hyperpolarized Chemical Exchange Saturation Transfer Pulse Sequence Parameter Optimization and Detectability Limit Assessment at 3.0T","year":2023,"lang":"en","type":"article","venue":"ChemPhysChem","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"NOSM University; Lakehead University; Thunder Bay Regional Research Institute","funders":"Mitacs","keywords":"Saturation (graph theory); Chemistry; Pulse sequence; Limit (mathematics); Front cover; Nuclear magnetic resonance; Analytical Chemistry (journal); Cover (algebra); Chemical physics; Physics; Chromatography; Engineering; Mathematics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005610392,0.0002699162,0.0003032182,0.00008460291,0.0002054181,0.0001663169,0.0002420155,0.0001819866,0.001929095],"category_scores_gemma":[0.0002510741,0.0002658092,0.0000769579,0.0004209302,0.0002128465,0.0004513898,0.00020821,0.0001642912,0.00009836882],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002206472,"about_ca_system_score_gemma":0.00005993394,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003030321,"about_ca_topic_score_gemma":0.000009189474,"domain_scores_codex":[0.9979257,0.0001210144,0.0003899291,0.0007041991,0.0004485887,0.0004105418],"domain_scores_gemma":[0.998827,0.0003672189,0.00007691997,0.0004440876,0.0001325916,0.0001522113],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003702163,0.00004043928,0.0003369866,0.0001249165,0.000005590639,0.000003223833,0.0002719824,0.0001972892,0.9966142,0.00009065265,0.0002598642,0.002017803],"study_design_scores_gemma":[0.0007257662,0.00004905955,0.001451625,0.00002129156,0.00002563157,0.00001318574,0.00002956213,0.07953843,0.9167188,0.0003723838,0.000721863,0.0003323955],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9921434,0.00007898583,0.005178166,0.0008872134,0.0002644907,0.0004891733,0.00005510552,0.000399632,0.0005038448],"genre_scores_gemma":[0.979347,0.00005297555,0.01963024,0.0001541189,0.0001267844,0.000205573,0.0001591393,0.00003435332,0.0002898092],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07989543,"threshold_uncertainty_score":0.9999794,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04032426177029069,"score_gpt":0.2845138333888938,"score_spread":0.2441895716186031,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}