{"id":"W4390224469","doi":"10.1021/acsomega.3c07533","title":"New Process for Na<sub>2</sub>CO<sub>3</sub> Production from Na<sub>2</sub>SO<sub>4</sub> Based on Modeling the Na<sub>2</sub>SO<sub>4</sub>–(NH<sub>4</sub>)<sub>2</sub>SO<sub>4</sub>–MEA–MEG–H<sub>2</sub>O System","year":2023,"lang":"en","type":"article","venue":"ACS Omega","topic":"Chemical and Physical Properties in Aqueous Solutions","field":"Chemical Engineering","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"National Natural Science Foundation of China; National Science Foundation","keywords":"Sodium sulfate; Aqueous solution; Crystallization; Anhydrous; Sodium; Sulfate; Solubility; Chemistry; Electrolyte; Chemical engineering; Process (computing); Materials science; Inorganic chemistry; Metallurgy; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.007404525,0.01410113,0.0121984,0.005165583,0.009829848,0.004761534,0.01145953,0.009162116,0.00005491248],"category_scores_gemma":[0.008061116,0.01429589,0.008401143,0.01605071,0.005016094,0.00696824,0.005392043,0.01650142,0.006997194],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.009895045,"about_ca_system_score_gemma":0.006126388,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004571531,"about_ca_topic_score_gemma":0.0009411792,"domain_scores_codex":[0.9370382,0.003300668,0.01393221,0.0167609,0.01228869,0.01667931],"domain_scores_gemma":[0.9585183,0.007108264,0.006789121,0.01348476,0.006021009,0.008078571],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.004709106,0.00408041,0.0001441702,0.006261193,0.003577141,0.0006411443,0.003150025,0.08101845,0.8103534,0.0007867353,0.02152849,0.06374974],"study_design_scores_gemma":[0.011387,0.001747553,0.0001854353,0.006987327,0.003934756,0.0006283025,0.001687087,0.1417089,0.8121809,0.004396341,0.001743712,0.01341264],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9295938,0.004942318,0.01784836,0.004162836,0.01050901,0.01549674,0.005255396,0.01132331,0.0008682454],"genre_scores_gemma":[0.9508598,0.006179221,0.0005200728,0.003362312,0.01464203,0.01000972,0.00872949,0.005606057,0.00009127099],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0606905,"threshold_uncertainty_score":0.999508,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02195165704519167,"score_gpt":0.2399335056754265,"score_spread":0.2179818486302348,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}