{"id":"W4390496104","doi":"10.1039/d3sc05403a","title":"Untangling ancillary ligand donation <i>versus</i> locus of oxidation effects on metal nitride reactivity","year":2024,"lang":"en","type":"article","venue":"Chemical Science","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"Alliance de recherche numérique du Canada; Natural Sciences and Engineering Research Council of Canada; Mitacs","keywords":"Reactivity (psychology); Locus (genetics); Donation; Ligand (biochemistry); Chemistry; Metal; Medicine; Biochemistry; Organic chemistry; Political science; Receptor; Gene","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004403713,0.0003498579,0.000249348,0.0001453543,0.0002180927,0.0007534641,0.0004839097,0.0002956179,0.003442412],"category_scores_gemma":[0.0009372753,0.000171816,0.0001567711,0.0001459056,0.0005110549,0.0007001274,0.0005330289,0.0005810041,0.0003332159],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002350426,"about_ca_system_score_gemma":0.0002355671,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002600587,"about_ca_topic_score_gemma":0.000640093,"domain_scores_codex":[0.9997476,0.00002970313,0.00001276532,0.00007173288,0.00009170498,0.00004654004],"domain_scores_gemma":[0.9996289,0.0001843575,0.00006714839,0.00005834804,0.00004027703,0.00002102419],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004048242,0.00005455904,0.001681663,0.0002059453,0.00002094367,0.000147604,0.0001428186,0.0004100337,0.9846955,0.003393431,0.0001767386,0.008666052],"study_design_scores_gemma":[0.00001109841,0.0002179622,0.002471682,0.00001477996,0.00002341469,0.0001154527,0.0001077521,0.002307983,0.9925207,0.0007277995,0.001465709,0.00001563096],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9827899,0.0004665148,0.007795056,0.0001351886,0.00005704313,0.00002508444,0.0002155283,0.0001547352,0.008360973],"genre_scores_gemma":[0.9961516,0.0003758418,0.002016863,0.00007195162,0.000009345931,0.00002174097,0.0001324356,0.0000425657,0.001177641],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003442412,"threshold_uncertainty_score":0.01151597,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00920373471735892,"score_gpt":0.2565930148907206,"score_spread":0.2473892801733617,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}