{"id":"W4390616180","doi":"10.1002/anie.202318829","title":"Guest‐Shuttling in a Nanosized Metallobox","year":2024,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"Wilfrid Laurier University","funders":"Ministerio de Ciencia e Innovación; Universitat Jaume I; Conselleria de Cultura, Educación y Ciencia, Generalitat Valenciana; Generalitat Valenciana","keywords":"Janus; Molecule; Planar; Chemistry; Ligand (biochemistry); Pyrazine; Iridium; Affinities; Nanotechnology; Chemical physics; Crystallography; Stereochemistry; Materials science; Receptor; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005766518,0.0001815254,0.0001760381,0.00007659508,0.0001209773,0.0002867275,0.0002273976,0.000175047,0.0007652143],"category_scores_gemma":[0.00005968343,0.0001330478,0.0001103525,0.00006659899,0.0001840713,0.0002105586,0.0002869575,0.0002843945,0.0002339533],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001576778,"about_ca_system_score_gemma":0.00008671603,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002476724,"about_ca_topic_score_gemma":0.0003781469,"domain_scores_codex":[0.9999458,0.00000396073,0.000002925081,0.00001975453,0.00001133497,0.00001618604],"domain_scores_gemma":[0.9999613,0.000005028981,0.00001145706,0.000004569421,0.000003762501,0.00001384558],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003119966,0.000008799839,0.00004467269,0.00002459273,0.000003169628,0.00007832985,0.00002407122,0.00009020191,0.9987015,0.000229326,0.00002678676,0.0007373849],"study_design_scores_gemma":[0.0000153028,0.0001875966,0.0007371074,0.000002223176,0.000009440226,0.0001792427,0.00001705662,0.001264845,0.9952139,0.00004639225,0.002320394,0.000006525192],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9951224,0.000216324,0.003115201,0.00004125927,0.0000197014,0.000009213083,0.00003859378,0.0001010891,0.001336179],"genre_scores_gemma":[0.9956771,0.0001086929,0.002352202,0.00001565757,0.000005450806,0.000009789992,0.00004370643,0.000016716,0.00177066],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007652143,"threshold_uncertainty_score":0.002559841,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01536098073990049,"score_gpt":0.26745041193073,"score_spread":0.2520894311908295,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}